Multi-component synthesis of spiro[diindeno[1,2-b:2′,1′-e]pyridine-11,3′-indoline]-triones using zinc terephthalate metal-organic frameworks

The present article describes an efficient one-pot method for the preparation of spiro[diindeno[1,2-b:2′,1′-e]pyridine-11,3′-indoline]-trione derivatives from a three-component condensation reaction of 1,3-indandione, aromatic amines and isatins in the presence of a zinc terephthalate metal-organic...

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Main Authors: Mohammad Ali Ghasemzadeh, Mohammad Hossein Abdollahi-Basir, Boshra Mirhosseini-Eshkevari
Format: Article
Language:English
Published: Taylor & Francis Group 2018-01-01
Series:Green Chemistry Letters and Reviews
Subjects:
Online Access:http://dx.doi.org/10.1080/17518253.2018.1434565
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spelling doaj-98955ed3a1fb4f9b88116f201d48125e2020-11-24T21:53:58ZengTaylor & Francis GroupGreen Chemistry Letters and Reviews1751-82531751-71922018-01-01111475310.1080/17518253.2018.14345651434565Multi-component synthesis of spiro[diindeno[1,2-b:2′,1′-e]pyridine-11,3′-indoline]-triones using zinc terephthalate metal-organic frameworksMohammad Ali Ghasemzadeh0Mohammad Hossein Abdollahi-Basir1Boshra Mirhosseini-Eshkevari2Islamic Azad UniversityIslamic Azad UniversityIslamic Azad UniversityThe present article describes an efficient one-pot method for the preparation of spiro[diindeno[1,2-b:2′,1′-e]pyridine-11,3′-indoline]-trione derivatives from a three-component condensation reaction of 1,3-indandione, aromatic amines and isatins in the presence of a zinc terephthalate metal-organic framework Zn (BDC) MOF as the catalyst under solvent-free conditions. High yields, short reaction times, simple workup and environmentally benign procedure are advantages of this protocol. The Zn (BDC) MOF catalyst can be recovered and reused several times without loss of activity. The catalyst was characterized by scanning electron microscopy, energy-dispersive X-ray spectroscopy, Fourier transform infra red, X-ray powder diffraction and thermal gravimetric analysis.http://dx.doi.org/10.1080/17518253.2018.1434565Spiro compoundsZn (BDC)multi-component reactionsmetal-organic frameworkssolvent-free
collection DOAJ
language English
format Article
sources DOAJ
author Mohammad Ali Ghasemzadeh
Mohammad Hossein Abdollahi-Basir
Boshra Mirhosseini-Eshkevari
spellingShingle Mohammad Ali Ghasemzadeh
Mohammad Hossein Abdollahi-Basir
Boshra Mirhosseini-Eshkevari
Multi-component synthesis of spiro[diindeno[1,2-b:2′,1′-e]pyridine-11,3′-indoline]-triones using zinc terephthalate metal-organic frameworks
Green Chemistry Letters and Reviews
Spiro compounds
Zn (BDC)
multi-component reactions
metal-organic frameworks
solvent-free
author_facet Mohammad Ali Ghasemzadeh
Mohammad Hossein Abdollahi-Basir
Boshra Mirhosseini-Eshkevari
author_sort Mohammad Ali Ghasemzadeh
title Multi-component synthesis of spiro[diindeno[1,2-b:2′,1′-e]pyridine-11,3′-indoline]-triones using zinc terephthalate metal-organic frameworks
title_short Multi-component synthesis of spiro[diindeno[1,2-b:2′,1′-e]pyridine-11,3′-indoline]-triones using zinc terephthalate metal-organic frameworks
title_full Multi-component synthesis of spiro[diindeno[1,2-b:2′,1′-e]pyridine-11,3′-indoline]-triones using zinc terephthalate metal-organic frameworks
title_fullStr Multi-component synthesis of spiro[diindeno[1,2-b:2′,1′-e]pyridine-11,3′-indoline]-triones using zinc terephthalate metal-organic frameworks
title_full_unstemmed Multi-component synthesis of spiro[diindeno[1,2-b:2′,1′-e]pyridine-11,3′-indoline]-triones using zinc terephthalate metal-organic frameworks
title_sort multi-component synthesis of spiro[diindeno[1,2-b:2′,1′-e]pyridine-11,3′-indoline]-triones using zinc terephthalate metal-organic frameworks
publisher Taylor & Francis Group
series Green Chemistry Letters and Reviews
issn 1751-8253
1751-7192
publishDate 2018-01-01
description The present article describes an efficient one-pot method for the preparation of spiro[diindeno[1,2-b:2′,1′-e]pyridine-11,3′-indoline]-trione derivatives from a three-component condensation reaction of 1,3-indandione, aromatic amines and isatins in the presence of a zinc terephthalate metal-organic framework Zn (BDC) MOF as the catalyst under solvent-free conditions. High yields, short reaction times, simple workup and environmentally benign procedure are advantages of this protocol. The Zn (BDC) MOF catalyst can be recovered and reused several times without loss of activity. The catalyst was characterized by scanning electron microscopy, energy-dispersive X-ray spectroscopy, Fourier transform infra red, X-ray powder diffraction and thermal gravimetric analysis.
topic Spiro compounds
Zn (BDC)
multi-component reactions
metal-organic frameworks
solvent-free
url http://dx.doi.org/10.1080/17518253.2018.1434565
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AT mohammadhosseinabdollahibasir multicomponentsynthesisofspirodiindeno12b21epyridine113indolinetrionesusingzincterephthalatemetalorganicframeworks
AT boshramirhosseinieshkevari multicomponentsynthesisofspirodiindeno12b21epyridine113indolinetrionesusingzincterephthalatemetalorganicframeworks
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