Bis(μ-diisopropylphosphanido-κ2P:P)bis[hydrido(triisopropylphosphane-κP)platinum(II)]

Bis(μ-diisopropylphosphanido-κ2P:P)bis[hydrido(triisopropylphosphane-κP)platinum(II)]

In the centrosymmetric molecular structure of the title compound [Pt2(C6H14P)2H2(C9H21P)2], each PtII atom is bound on one side to a phosphane ligand (PiPr3) and a hydrido ligand. On the other side, it is bound to two phosphanide ligands (μ-PiPr2), which engage a bridging position betwe...

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Main Authors: Nicole Arnold, Holger Braunschweig, Alexander Damme
Format: Article
Language:English
Published: International Union of Crystallography 2012-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812022829
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spelling doaj-982d2e48d20f4c3cb09d730097984c4b2020-11-25T01:50:50ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-06-01686m808m80810.1107/S1600536812022829Bis(μ-diisopropylphosphanido-κ2P:P)bis[hydrido(triisopropylphosphane-κP)platinum(II)]Nicole ArnoldHolger BraunschweigAlexander DammeIn the centrosymmetric molecular structure of the title compound [Pt2(C6H14P)2H2(C9H21P)2], each PtII atom is bound on one side to a phosphane ligand (PiPr3) and a hydrido ligand. On the other side, it is bound to two phosphanide ligands (μ-PiPr2), which engage a bridging position between the two PtII atoms, forming a distorted square-planar structure motif. The Pt...Pt distance is 3.6755 (2) Å. A comparable molecular structure was observed for bis(μ-di-tert-butylphosphanido)bis[hydrido(triethylphosphane)platinum(II)] [Itazaki et al. (2004). Organometallics, 23, 1610–1621].http://scripts.iucr.org/cgi-bin/paper?S1600536812022829
collection DOAJ
language English
format Article
sources DOAJ
author Nicole Arnold
Holger Braunschweig
Alexander Damme
spellingShingle Nicole Arnold
Holger Braunschweig
Alexander Damme
Bis(μ-diisopropylphosphanido-κ2P:P)bis[hydrido(triisopropylphosphane-κP)platinum(II)]
Acta Crystallographica Section E
author_facet Nicole Arnold
Holger Braunschweig
Alexander Damme
author_sort Nicole Arnold
title Bis(μ-diisopropylphosphanido-κ2P:P)bis[hydrido(triisopropylphosphane-κP)platinum(II)]
title_short Bis(μ-diisopropylphosphanido-κ2P:P)bis[hydrido(triisopropylphosphane-κP)platinum(II)]
title_full Bis(μ-diisopropylphosphanido-κ2P:P)bis[hydrido(triisopropylphosphane-κP)platinum(II)]
title_fullStr Bis(μ-diisopropylphosphanido-κ2P:P)bis[hydrido(triisopropylphosphane-κP)platinum(II)]
title_full_unstemmed Bis(μ-diisopropylphosphanido-κ2P:P)bis[hydrido(triisopropylphosphane-κP)platinum(II)]
title_sort bis(μ-diisopropylphosphanido-κ2p:p)bis[hydrido(triisopropylphosphane-κp)platinum(ii)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-06-01
description In the centrosymmetric molecular structure of the title compound [Pt2(C6H14P)2H2(C9H21P)2], each PtII atom is bound on one side to a phosphane ligand (PiPr3) and a hydrido ligand. On the other side, it is bound to two phosphanide ligands (μ-PiPr2), which engage a bridging position between the two PtII atoms, forming a distorted square-planar structure motif. The Pt...Pt distance is 3.6755 (2) Å. A comparable molecular structure was observed for bis(μ-di-tert-butylphosphanido)bis[hydrido(triethylphosphane)platinum(II)] [Itazaki et al. (2004). Organometallics, 23, 1610–1621].
url http://scripts.iucr.org/cgi-bin/paper?S1600536812022829
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AT holgerbraunschweig bisamp956diisopropylphosphanidoamp9542ppbishydridotriisopropylphosphaneamp954pplatinumii
AT alexanderdamme bisamp956diisopropylphosphanidoamp9542ppbishydridotriisopropylphosphaneamp954pplatinumii
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