Soybean epoxide production with in situ peracetic acid using homogeneous catalysis

Using vegetable oils has become an excellent option for petrochemical product substitution. The epoxides obtained from such oils have wide applications as plastifiers and PVC stabilisers and as raw material in polyol synthesis for the polyurethane industry. This paper presents soybean oil epoxidatio...

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Bibliographic Details
Main Authors: Luis Alejandro Boyacá Mendivelso, Ángela Aurora Beltrán
Format: Article
Language:English
Published: Universidad Nacional de Colombia 2010-01-01
Series:Ingeniería e Investigación
Subjects:
Online Access:https://revistas.unal.edu.co/index.php/ingeinv/article/view/15222
Description
Summary:Using vegetable oils has become an excellent option for petrochemical product substitution. The epoxides obtained from such oils have wide applications as plastifiers and PVC stabilisers and as raw material in polyol synthesis for the polyurethane industry. This paper presents soybean oil epoxidation using a homogeneous catalyst in a well-mixed, stirred reactor being operated in iso- thermal conditions. The best result achieved was a 6.4% oxyrane oxygen content using hydrogen peroxide (25% molar excess), a- cetic acid (5% p/p) and sulphuric acid (2% p/p) concentrations at 80°C.
ISSN:0120-5609
2248-8723