Tributylammonium chlorochromate, (C4H9)3NH[CrO3Cl](TriBACC): A new, mild and stable oxidant for organic substrates
A mild and stable new chromium(VI) reagent from tributylamine is described. Orange crystalline tributylammonium chlorochromate(VI), (C4H9)3NH[CrO3Cl], (TriBACC), is easily prepared in a nearly quantitative yield by the interaction of tributylamine with CrO3 and hydrochloric acid in a 1:2:2 mole rati...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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Serbian Chemical Society
2005-05-01
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| Series: | Journal of the Serbian Chemical Society |
| Subjects: | |
| Online Access: | http://www.shd.org.yu/HtDocs/SHD/vol70/No5/JSCS_V70_No5-02.pdf |
| Summary: | A mild and stable new chromium(VI) reagent from tributylamine is described. Orange crystalline tributylammonium chlorochromate(VI), (C4H9)3NH[CrO3Cl], (TriBACC), is easily prepared in a nearly quantitative yield by the interaction of tributylamine with CrO3 and hydrochloric acid in a 1:2:2 mole ratio. This reagent is a versatile reagent for the effective and selective oxidation of organic substrates, in particular for alcohols, under mild conditions. |
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| ISSN: | 0352-5139 |