CATIONIC COORDINATION COMPOUNDS [Ln(Pip)2(Ph3PO)3]B(Ph)4 BASED ON 2,2,2-TRICHLORO-N-(DIPIPERIDIN-1-YL-PHOSPHORYL)ACETAMIDE

CATIONIC COORDINATION COMPOUNDS [Ln(Pip)2(Ph3PO)3]B(Ph)4 BASED ON 2,2,2-TRICHLORO-N-(DIPIPERIDIN-1-YL-PHOSPHORYL)ACETAMIDE

A series of cationic complexes [Ln(Pip)2(Ph3PO)3]B(Ph)4·2H2O (Ln(III) = La, Nd, Еu, Lu;  HPip (CAPh type ligand) = 2,2,2-trichloro-N-(dipiperidin-1-yl-phosphoryl)acetamide) has been synthesized. The complexes have been characterized by means of the X-ray diffraction,  FT-IR spectroscopy and elementa...

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Main Authors: O. О. Litsis, Т. Yu Sliva, S. V. Shishkina, V. M. Аmirkhanov
Format: Article
Language:English
Published: Odessa I. I. Mechnikov National University 2016-07-01
Series:Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ
Subjects:
карбациламідофосфат
хелатуючий О,О’-ліганд
лантаноїд
катіонний комплекс
Online Access:http://heraldchem.onu.edu.ua/article/view/74779
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spelling doaj-970c3525e7084d6b9ea4e5639ad425e62020-11-25T00:59:47ZengOdessa I. I. Mechnikov National University Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ2304-09472414-59632016-07-01212(58)293710.18524/2304-0947.2016.2(58).7477974779CATIONIC COORDINATION COMPOUNDS [Ln(Pip)2(Ph3PO)3]B(Ph)4 BASED ON 2,2,2-TRICHLORO-N-(DIPIPERIDIN-1-YL-PHOSPHORYL)ACETAMIDEO. О. Litsis0Т. Yu Sliva1S. V. Shishkina2V. M. Аmirkhanov3Київський національний університет імені Тараса Шевченка, хімічний факультет, кафедра неорганічної хіміїКиївський національний університет імені Тараса Шевченка, хімічний факультет, кафедра неорганічної хіміїНТК «Інститут монокристалів» НАН УкраїниКиївський національний університет імені Тараса Шевченка, хімічний факультет, кафедра неорганічної хіміїA series of cationic complexes [Ln(Pip)2(Ph3PO)3]B(Ph)4·2H2O (Ln(III) = La, Nd, Еu, Lu;  HPip (CAPh type ligand) = 2,2,2-trichloro-N-(dipiperidin-1-yl-phosphoryl)acetamide) has been synthesized. The complexes have been characterized by means of the X-ray diffraction,  FT-IR spectroscopy and elemental analyse. Crystal structure of [Lа(Pip)2(Ph3PO)3] B(Ph)4·2H2O has been determined. Cell edge parameters: a = 15.3820 Å, b = 15.2050 Å, c =44.8980 Å, β = 92.98°, V = 10486.7Å3, space group P 21/c. Two CAPh ligands are coordinated via oxygen atoms of phosphoryl and carbonyl groups, forming six-membered cycles Schemes of [Lа(Pip)2(Ph3PO)3]BPh4·2H2O dissociation in nonaqueous solvents: acetone and methanol has been investigated. To determine the type of electrolyte value of electric conductivity at infinite dilution (λ0) was calculated.http://heraldchem.onu.edu.ua/article/view/74779карбациламідофосфатхелатуючий О,О’-лігандлантаноїдкатіонний комплекс
collection DOAJ
language English
format Article
sources DOAJ
author O. О. Litsis
Т. Yu Sliva
S. V. Shishkina
V. M. Аmirkhanov
spellingShingle O. О. Litsis
Т. Yu Sliva
S. V. Shishkina
V. M. Аmirkhanov
CATIONIC COORDINATION COMPOUNDS [Ln(Pip)2(Ph3PO)3]B(Ph)4 BASED ON 2,2,2-TRICHLORO-N-(DIPIPERIDIN-1-YL-PHOSPHORYL)ACETAMIDE
Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ
карбациламідофосфат
хелатуючий О,О’-ліганд
лантаноїд
катіонний комплекс
author_facet O. О. Litsis
Т. Yu Sliva
S. V. Shishkina
V. M. Аmirkhanov
author_sort O. О. Litsis
title CATIONIC COORDINATION COMPOUNDS [Ln(Pip)2(Ph3PO)3]B(Ph)4 BASED ON 2,2,2-TRICHLORO-N-(DIPIPERIDIN-1-YL-PHOSPHORYL)ACETAMIDE
title_short CATIONIC COORDINATION COMPOUNDS [Ln(Pip)2(Ph3PO)3]B(Ph)4 BASED ON 2,2,2-TRICHLORO-N-(DIPIPERIDIN-1-YL-PHOSPHORYL)ACETAMIDE
title_full CATIONIC COORDINATION COMPOUNDS [Ln(Pip)2(Ph3PO)3]B(Ph)4 BASED ON 2,2,2-TRICHLORO-N-(DIPIPERIDIN-1-YL-PHOSPHORYL)ACETAMIDE
title_fullStr CATIONIC COORDINATION COMPOUNDS [Ln(Pip)2(Ph3PO)3]B(Ph)4 BASED ON 2,2,2-TRICHLORO-N-(DIPIPERIDIN-1-YL-PHOSPHORYL)ACETAMIDE
title_full_unstemmed CATIONIC COORDINATION COMPOUNDS [Ln(Pip)2(Ph3PO)3]B(Ph)4 BASED ON 2,2,2-TRICHLORO-N-(DIPIPERIDIN-1-YL-PHOSPHORYL)ACETAMIDE
title_sort cationic coordination compounds [ln(pip)2(ph3po)3]b(ph)4 based on 2,2,2-trichloro-n-(dipiperidin-1-yl-phosphoryl)acetamide
publisher Odessa I. I. Mechnikov National University
series Vìsnik Odesʹkogo Nacìonalʹnogo Unìversitetu: Hìmìâ
issn 2304-0947
2414-5963
publishDate 2016-07-01
description A series of cationic complexes [Ln(Pip)2(Ph3PO)3]B(Ph)4·2H2O (Ln(III) = La, Nd, Еu, Lu;  HPip (CAPh type ligand) = 2,2,2-trichloro-N-(dipiperidin-1-yl-phosphoryl)acetamide) has been synthesized. The complexes have been characterized by means of the X-ray diffraction,  FT-IR spectroscopy and elemental analyse. Crystal structure of [Lа(Pip)2(Ph3PO)3] B(Ph)4·2H2O has been determined. Cell edge parameters: a = 15.3820 Å, b = 15.2050 Å, c =44.8980 Å, β = 92.98°, V = 10486.7Å3, space group P 21/c. Two CAPh ligands are coordinated via oxygen atoms of phosphoryl and carbonyl groups, forming six-membered cycles Schemes of [Lа(Pip)2(Ph3PO)3]BPh4·2H2O dissociation in nonaqueous solvents: acetone and methanol has been investigated. To determine the type of electrolyte value of electric conductivity at infinite dilution (λ0) was calculated.
topic карбациламідофосфат
хелатуючий О,О’-ліганд
лантаноїд
катіонний комплекс
url http://heraldchem.onu.edu.ua/article/view/74779
work_keys_str_mv AT oolitsis cationiccoordinationcompoundslnpip2ph3po3bph4basedon222trichlorondipiperidin1ylphosphorylacetamide
AT tyusliva cationiccoordinationcompoundslnpip2ph3po3bph4basedon222trichlorondipiperidin1ylphosphorylacetamide
AT svshishkina cationiccoordinationcompoundslnpip2ph3po3bph4basedon222trichlorondipiperidin1ylphosphorylacetamide
AT vmamirkhanov cationiccoordinationcompoundslnpip2ph3po3bph4basedon222trichlorondipiperidin1ylphosphorylacetamide
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