trans-Aqua(4,7-diazadecane-1,10-diamine-κ4N)fluoridochromium(III) bis(perchlorate) monohydrate

trans-Aqua(4,7-diazadecane-1,10-diamine-κ4N)fluoridochromium(III) bis(perchlorate) monohydrate

In the title compound, [CrF(C8H20N4)(H2O)](ClO4)2·H2O, the Cr atom is in a slightly distorted octahedral environment, coordinated by four N atoms of the 4,7-diazadecane-1,10-diamine ligand, one water molecule and an F atom trans to water. The five-membered chelate ring is in a gauche form,...

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Main Authors: Uk Lee, Jong-Ha Choi
Format: Article
Language:English
Published: International Union of Crystallography 2008-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808026081
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spelling doaj-96c4c9d79c0e435dbc7a058c9ba9f75a2020-11-25T01:13:22ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-09-01649m1186m118610.1107/S1600536808026081trans-Aqua(4,7-diazadecane-1,10-diamine-κ4N)fluoridochromium(III) bis(perchlorate) monohydrateUk LeeJong-Ha ChoiIn the title compound, [CrF(C8H20N4)(H2O)](ClO4)2·H2O, the Cr atom is in a slightly distorted octahedral environment, coordinated by four N atoms of the 4,7-diazadecane-1,10-diamine ligand, one water molecule and an F atom trans to water. The five-membered chelate ring is in a gauche form, while the two six-membered chelate rings are in chair conformations. The crystal structure is stabilized by several hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536808026081
collection DOAJ
language English
format Article
sources DOAJ
author Uk Lee
Jong-Ha Choi
spellingShingle Uk Lee
Jong-Ha Choi
trans-Aqua(4,7-diazadecane-1,10-diamine-κ4N)fluoridochromium(III) bis(perchlorate) monohydrate
Acta Crystallographica Section E
author_facet Uk Lee
Jong-Ha Choi
author_sort Uk Lee
title trans-Aqua(4,7-diazadecane-1,10-diamine-κ4N)fluoridochromium(III) bis(perchlorate) monohydrate
title_short trans-Aqua(4,7-diazadecane-1,10-diamine-κ4N)fluoridochromium(III) bis(perchlorate) monohydrate
title_full trans-Aqua(4,7-diazadecane-1,10-diamine-κ4N)fluoridochromium(III) bis(perchlorate) monohydrate
title_fullStr trans-Aqua(4,7-diazadecane-1,10-diamine-κ4N)fluoridochromium(III) bis(perchlorate) monohydrate
title_full_unstemmed trans-Aqua(4,7-diazadecane-1,10-diamine-κ4N)fluoridochromium(III) bis(perchlorate) monohydrate
title_sort trans-aqua(4,7-diazadecane-1,10-diamine-κ4n)fluoridochromium(iii) bis(perchlorate) monohydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-09-01
description In the title compound, [CrF(C8H20N4)(H2O)](ClO4)2·H2O, the Cr atom is in a slightly distorted octahedral environment, coordinated by four N atoms of the 4,7-diazadecane-1,10-diamine ligand, one water molecule and an F atom trans to water. The five-membered chelate ring is in a gauche form, while the two six-membered chelate rings are in chair conformations. The crystal structure is stabilized by several hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808026081
work_keys_str_mv AT uklee transaqua47diazadecane110diamine9544nfluoridochromiumiiibisperchloratemonohydrate
AT jonghachoi transaqua47diazadecane110diamine9544nfluoridochromiumiiibisperchloratemonohydrate
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