Crystal structure and Hirshfeld surface analysis of [2-(1H-benzimidazol-2-yl-κN3)aniline-κN]dichloridozinc(II) N,N-dimethylformamide monosolvate

Crystal structure and Hirshfeld surface analysis of [2-(1H-benzimidazol-2-yl-κN3)aniline-κN]dichloridozinc(II) N,N-dimethylformamide monosolvate

The title compound, [ZnCl2(C13H11N3)]·C3H7NO, crystallized in the monoclinic crystal system in space group P21/n. The asymmetric unit contains one neutral complex molecule, which consists of a zinc ion, a bidentate ligand, and two chlorido ligands with dimethylformamide monosolvate. The ligand has t...

Full description

Bibliographic Details
Main Authors: Mohd Muslim, Md. Serajul Haque Faizi, Arif Ali, Mohd Afzal, Musheer Ahmad, Necmi Dege, Ashraf Mashrai
Format: Article
Language:English
Published: International Union of Crystallography 2021-05-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
benzimidazole
aniline
bidentate ligand
heterocyclic
zinc(ii) complex
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989021003649
Description
Summary:The title compound, [ZnCl2(C13H11N3)]·C3H7NO, crystallized in the monoclinic crystal system in space group P21/n. The asymmetric unit contains one neutral complex molecule, which consists of a zinc ion, a bidentate ligand, and two chlorido ligands with dimethylformamide monosolvate. The ligand has two moieties, a benzimidazole and an aniline group. The benzimidazole and aniline planes are not coplanar, subtending a dihedral angle of 18.24 (8)°. The Zn(II) ion shows distorted tetrahedral geometry, being coordinated by an imidazole N atom, the aniline N atom, and two chlorido ligands. The packing features N—H...O, N—H...Cl, C—H...Cl hydrogen bonding.
ISSN:2056-9890

Similar Items