Tetraethylammonium tetrakis(1,1,1,5,5,5-hexafluoroacetylacetonato)terbate(III)

Tetraethylammonium tetrakis(1,1,1,5,5,5-hexafluoroacetylacetonato)terbate(III)

The title compound, (C8H20N)[Tb(C5HF6O2)4], is a tetrakis β-diketonate complex of hexafluoroacetylacetone with terbium(III), and tetraethylammonium as the counter-ion. This compound shows typical green terbium(III) luminescence upon excitation at about 335 nm. The coordina...

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Main Authors: Rik Van Deun, Pascal Van Der Voort, Isabel Van Driessche, Kristof Van Hecke
Format: Article
Language:English
Published: International Union of Crystallography 2012-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811055437
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spelling doaj-9638e45734bd4df48f5fcde9f69ff1d52020-11-24T21:32:20ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-02-01682m111m11210.1107/S1600536811055437Tetraethylammonium tetrakis(1,1,1,5,5,5-hexafluoroacetylacetonato)terbate(III)Rik Van DeunPascal Van Der VoortIsabel Van DriesscheKristof Van HeckeThe title compound, (C8H20N)[Tb(C5HF6O2)4], is a tetrakis β-diketonate complex of hexafluoroacetylacetone with terbium(III), and tetraethylammonium as the counter-ion. This compound shows typical green terbium(III) luminescence upon excitation at about 335 nm. The coordination geometry around the TbIII atom is a slightly distorted square antiprism. One hexafluoroacetylacetone ligand has a disordered CF3 group [occupancies of 0.575 (4) and 0.425 (4)]. A three-dimensional network is built up by linkage of TbIII complexes via C—H...F interactions.http://scripts.iucr.org/cgi-bin/paper?S1600536811055437
collection DOAJ
language English
format Article
sources DOAJ
author Rik Van Deun
Pascal Van Der Voort
Isabel Van Driessche
Kristof Van Hecke
spellingShingle Rik Van Deun
Pascal Van Der Voort
Isabel Van Driessche
Kristof Van Hecke
Tetraethylammonium tetrakis(1,1,1,5,5,5-hexafluoroacetylacetonato)terbate(III)
Acta Crystallographica Section E
author_facet Rik Van Deun
Pascal Van Der Voort
Isabel Van Driessche
Kristof Van Hecke
author_sort Rik Van Deun
title Tetraethylammonium tetrakis(1,1,1,5,5,5-hexafluoroacetylacetonato)terbate(III)
title_short Tetraethylammonium tetrakis(1,1,1,5,5,5-hexafluoroacetylacetonato)terbate(III)
title_full Tetraethylammonium tetrakis(1,1,1,5,5,5-hexafluoroacetylacetonato)terbate(III)
title_fullStr Tetraethylammonium tetrakis(1,1,1,5,5,5-hexafluoroacetylacetonato)terbate(III)
title_full_unstemmed Tetraethylammonium tetrakis(1,1,1,5,5,5-hexafluoroacetylacetonato)terbate(III)
title_sort tetraethylammonium tetrakis(1,1,1,5,5,5-hexafluoroacetylacetonato)terbate(iii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-02-01
description The title compound, (C8H20N)[Tb(C5HF6O2)4], is a tetrakis β-diketonate complex of hexafluoroacetylacetone with terbium(III), and tetraethylammonium as the counter-ion. This compound shows typical green terbium(III) luminescence upon excitation at about 335 nm. The coordination geometry around the TbIII atom is a slightly distorted square antiprism. One hexafluoroacetylacetone ligand has a disordered CF3 group [occupancies of 0.575 (4) and 0.425 (4)]. A three-dimensional network is built up by linkage of TbIII complexes via C—H...F interactions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811055437
work_keys_str_mv AT rikvandeun tetraethylammoniumtetrakis111555hexafluoroacetylacetonatoterbateiii
AT pascalvandervoort tetraethylammoniumtetrakis111555hexafluoroacetylacetonatoterbateiii
AT isabelvandriessche tetraethylammoniumtetrakis111555hexafluoroacetylacetonatoterbateiii
AT kristofvanhecke tetraethylammoniumtetrakis111555hexafluoroacetylacetonatoterbateiii
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