Insulated conjugated bimetallopolymer with sigmoidal response by dual self-controlling system as a biomimetic material

Molecules can serve as biomimetic sensors, but dual self-controlling systems that involve self-activation and self-regulation are difficult to mimic. Here the authors report an insulated conjugated bimetallopolymer with cooperative multiple transition metals that phosphoresces in response to carbon...

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Main Authors:	Hiroshi Masai, Takuya Yokoyama, Hiromichi V. Miyagishi, Maning Liu, Yasuhiro Tachibana, Tetsuaki Fujihara, Yasushi Tsuji, Jun Terao
Format:	Article
Language:	English
Published:	Nature Publishing Group 2020-01-01
Series:	Nature Communications
Online Access:	https://doi.org/10.1038/s41467-019-14271-2

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spelling	doaj-95e4403b426d458d96efb6ce691f2baf2021-05-11T09:18:14ZengNature Publishing GroupNature Communications2041-17232020-01-011111810.1038/s41467-019-14271-2Insulated conjugated bimetallopolymer with sigmoidal response by dual self-controlling system as a biomimetic materialHiroshi Masai0Takuya Yokoyama1Hiromichi V. Miyagishi2Maning Liu3Yasuhiro Tachibana4Tetsuaki Fujihara5Yasushi Tsuji6Jun Terao7Department of Basic Science, Graduate School of Arts and Sciences, The University of TokyoDepartment of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto UniversityDepartment of Basic Science, Graduate School of Arts and Sciences, The University of TokyoSchool of Engineering, RMIT University, BundooraSchool of Engineering, RMIT University, BundooraDepartment of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto UniversityDepartment of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto UniversityDepartment of Basic Science, Graduate School of Arts and Sciences, The University of TokyoMolecules can serve as biomimetic sensors, but dual self-controlling systems that involve self-activation and self-regulation are difficult to mimic. Here the authors report an insulated conjugated bimetallopolymer with cooperative multiple transition metals that phosphoresces in response to carbon monoxide.https://doi.org/10.1038/s41467-019-14271-2
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Hiroshi Masai Takuya Yokoyama Hiromichi V. Miyagishi Maning Liu Yasuhiro Tachibana Tetsuaki Fujihara Yasushi Tsuji Jun Terao
spellingShingle	Hiroshi Masai Takuya Yokoyama Hiromichi V. Miyagishi Maning Liu Yasuhiro Tachibana Tetsuaki Fujihara Yasushi Tsuji Jun Terao Insulated conjugated bimetallopolymer with sigmoidal response by dual self-controlling system as a biomimetic material Nature Communications
author_facet	Hiroshi Masai Takuya Yokoyama Hiromichi V. Miyagishi Maning Liu Yasuhiro Tachibana Tetsuaki Fujihara Yasushi Tsuji Jun Terao
author_sort	Hiroshi Masai
title	Insulated conjugated bimetallopolymer with sigmoidal response by dual self-controlling system as a biomimetic material
title_short	Insulated conjugated bimetallopolymer with sigmoidal response by dual self-controlling system as a biomimetic material
title_full	Insulated conjugated bimetallopolymer with sigmoidal response by dual self-controlling system as a biomimetic material
title_fullStr	Insulated conjugated bimetallopolymer with sigmoidal response by dual self-controlling system as a biomimetic material
title_full_unstemmed	Insulated conjugated bimetallopolymer with sigmoidal response by dual self-controlling system as a biomimetic material
title_sort	insulated conjugated bimetallopolymer with sigmoidal response by dual self-controlling system as a biomimetic material
publisher	Nature Publishing Group
series	Nature Communications
issn	2041-1723
publishDate	2020-01-01
description	Molecules can serve as biomimetic sensors, but dual self-controlling systems that involve self-activation and self-regulation are difficult to mimic. Here the authors report an insulated conjugated bimetallopolymer with cooperative multiple transition metals that phosphoresces in response to carbon monoxide.
url	https://doi.org/10.1038/s41467-019-14271-2
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Insulated conjugated bimetallopolymer with sigmoidal response by dual self-controlling system as a biomimetic material

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