Crystal structures of four new iridium complexes, each containing a highly flexible carbodiphosphorane PCP pincer ligand

Crystal structures of four new iridium complexes, each containing a highly flexible carbodiphosphorane PCP pincer ligand

Compound [Ir(C8H12)(C51H45P4)]Cl2 or [Ir(cod)(CH(dppm)2-κ3P,C,P)]Cl2 (1a), was obtained from [IrCl(cod)]2 and the carbodiphosphorane (CDP) salt [CH(dppm)2]Cl [where cod = cycloocta-1,5-diene and dppm = bis(diphenylphosphino)methane]. Treatment of 1a with thallium(I) trifluoromethanesulfonate [Tl(OTf...

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Bibliographic Details
Main Authors: Gabriel Julian Partl, Felix Nussbaumer, Inge Schlapp-Hackl, Walter Schuh, Holger Kopacka, Klaus Wurst, Paul Peringer
Format: Article
Language:English
Published: International Union of Crystallography 2018-06-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
iridium
PCP pincer ligand
carbodiphosphorane
hydride
carbonyl
cyclooctadiene
oxidative addition
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989018007569

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http://scripts.iucr.org/cgi-bin/paper?S2056989018007569

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