Hydronium 4-oxo-1,4-dihydropyridine-3-sulfonate dihydrate

2-Hydroxypyridine when treated with concentrated sulfuric acid is sulfonated at the 3-position to yield the title hydrated salt, H3O+·C5H4NO3S−·2H2O. In the crystal structure, the cations, anions and uncoordinated water molecules are linked by extensive O&...

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Bibliographic Details
Main Authors: Zhi-Biao Zhu, Shan Gao, Seik Weng Ng
Format: Article
Language:English
Published: International Union of Crystallography 2009-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809040641
Description
Summary:2-Hydroxypyridine when treated with concentrated sulfuric acid is sulfonated at the 3-position to yield the title hydrated salt, H3O+·C5H4NO3S−·2H2O. In the crystal structure, the cations, anions and uncoordinated water molecules are linked by extensive O—H...O and N—H...O hydrogen bonds into a three-dimensional network. The crystal studied is a non-merohedral twin with a twin component of 36%.
ISSN:1600-5368