(E)-N′-[4-(Dimethylamino)benzylidene]-4-hydroxybenzohydrazide hemihydrate

In the title compound, C16H17N3O2·0.5H2O, the two hydrazide molecules are approximately planar: the dihedral angles between the two substituted benzene rings are 7.7 (2) and 4.2 (2)°. Both hydrazone molecules exist in a trans geometry with respec...

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Bibliographic Details
Main Author: Huanyu Liu
Format: Article
Language:English
Published: International Union of Crystallography 2010-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810020763
Description
Summary:In the title compound, C16H17N3O2·0.5H2O, the two hydrazide molecules are approximately planar: the dihedral angles between the two substituted benzene rings are 7.7 (2) and 4.2 (2)°. Both hydrazone molecules exist in a trans geometry with respect to their methylidene units. In the crystal, the water molecule lies between the two organic molecules and makes bifurcated O—H...(N,O) hydrogen bonds to both of them. The hydrazide molecules form N—H...O and O—H...O hydrogen bonds, resulting in a three-dimensional network.
ISSN:1600-5368