catena-Poly[[(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)lead(II)]-di-μ-bromido]

catena-Poly[[(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)lead(II)]-di-μ-bromido]

In the title compound, [PbBr2(C14H12N2)]n, the PbII atom lies on a twofold rotation axis. The N-heterocycle-chelated PbII atom exists in a distorted octahedral geometry owing to two long Pb...Br interactions [2.9562 (5) and 3.2594 (5) Å]. These...

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Main Authors: Behrous Sabour, Ezzatollah Najafi, Mostafa M. Amini, Seik Weng Ng
Format: Article
Language:English
Published: International Union of Crystallography 2012-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681201940X
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spelling doaj-9564454f3f10441b905f011c1f6240482020-11-25T01:39:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-06-01686m729m72910.1107/S160053681201940Xcatena-Poly[[(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)lead(II)]-di-μ-bromido]Behrous SabourEzzatollah NajafiMostafa M. AminiSeik Weng NgIn the title compound, [PbBr2(C14H12N2)]n, the PbII atom lies on a twofold rotation axis. The N-heterocycle-chelated PbII atom exists in a distorted octahedral geometry owing to two long Pb...Br interactions [2.9562 (5) and 3.2594 (5) Å]. These result in a zigzag chain running along the c axis. The lone pair is stereochemically inactive.http://scripts.iucr.org/cgi-bin/paper?S160053681201940X
collection DOAJ
language English
format Article
sources DOAJ
author Behrous Sabour
Ezzatollah Najafi
Mostafa M. Amini
Seik Weng Ng
spellingShingle Behrous Sabour
Ezzatollah Najafi
Mostafa M. Amini
Seik Weng Ng
catena-Poly[[(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)lead(II)]-di-μ-bromido]
Acta Crystallographica Section E
author_facet Behrous Sabour
Ezzatollah Najafi
Mostafa M. Amini
Seik Weng Ng
author_sort Behrous Sabour
title catena-Poly[[(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)lead(II)]-di-μ-bromido]
title_short catena-Poly[[(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)lead(II)]-di-μ-bromido]
title_full catena-Poly[[(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)lead(II)]-di-μ-bromido]
title_fullStr catena-Poly[[(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)lead(II)]-di-μ-bromido]
title_full_unstemmed catena-Poly[[(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)lead(II)]-di-μ-bromido]
title_sort catena-poly[[(2,9-dimethyl-1,10-phenanthroline-κ2n,n′)lead(ii)]-di-μ-bromido]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-06-01
description In the title compound, [PbBr2(C14H12N2)]n, the PbII atom lies on a twofold rotation axis. The N-heterocycle-chelated PbII atom exists in a distorted octahedral geometry owing to two long Pb...Br interactions [2.9562 (5) and 3.2594 (5) Å]. These result in a zigzag chain running along the c axis. The lone pair is stereochemically inactive.
url http://scripts.iucr.org/cgi-bin/paper?S160053681201940X
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AT ezzatollahnajafi catenapoly29dimethyl110phenanthrolineamp9542nnamp8242leadiidiamp956bromido
AT mostafamamini catenapoly29dimethyl110phenanthrolineamp9542nnamp8242leadiidiamp956bromido
AT seikwengng catenapoly29dimethyl110phenanthrolineamp9542nnamp8242leadiidiamp956bromido
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