| Summary: | The flame resistance of applied coating materials affects the safety of innovative technological solutions. Silicone-containing polymeric materials are one of the most economical solutions in the field of coatings due to the effect of the unique combination of very good thermal, resistance, and surface properties. The rich chemistry of silicon compounds, which results in their very good thermal stability, allows their use as flame-resistant coating materials or as flame retardants in polymer composites. In this review, the flame resistance of PDMS systems based on their thermal degradation data, as well as possible paths of thermal degradation depending on external conditions including the effect of additives, flame resistance of hybrid silicone-containing coating materials and most important innovative applications of these materials, are reviewed. Very good results from the use of organic silicon compounds as fire retardants in polymers obtained by many research teams are one of the promising ways of overcoming the health, safety, and availability concerns of traditional halogenated fire retardants.
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