Crystal structure of (1S,2R)-6,6-dimethyl-4,8-dioxo-2-phenylspiro[2.5]octane-1-carbaldehyde

Crystal structure of (1S,2R)-6,6-dimethyl-4,8-dioxo-2-phenylspiro[2.5]octane-1-carbaldehyde

In the title compound, C17H18O3, the two non-spiro C atoms of the cyclopropane ring bear a formyl and a phenyl substituent which are trans-oriented. In the crystal, molecules are linked by weak C—H...O and C—H...π contacts resulting in a three-dimensional supramolecular structure.

Bibliographic Details
Main Authors: Saloua Chelli, Konstantin Troshin, Sami Lakhdar, Herbert Mayr, Peter Mayer
Format: Article
Language:English
Published: International Union of Crystallography 2016-02-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
substituted spiro-cyclopropanes
weak C—H...O and C—H...π interactions
Online Access:http://scripts.iucr.org/cgi-bin/paper?S205698901600164X
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spelling doaj-950eb5b78bd04d88a6ce719242c749642020-11-24T23:58:52ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902016-02-0172226626810.1107/S205698901600164Xsu5275Crystal structure of (1S,2R)-6,6-dimethyl-4,8-dioxo-2-phenylspiro[2.5]octane-1-carbaldehydeSaloua Chelli0Konstantin Troshin1Sami Lakhdar2Herbert Mayr3Peter Mayer4Ludwig-Maximilians-Universität, Department, Butenandtstrasse 5–13, 81377 München, GermanyLudwig-Maximilians-Universität, Department, Butenandtstrasse 5–13, 81377 München, GermanyLudwig-Maximilians-Universität, Department, Butenandtstrasse 5–13, 81377 München, GermanyLudwig-Maximilians-Universität, Department, Butenandtstrasse 5–13, 81377 München, GermanyDepartment Chemie und Biochemie, Ludwig-Maximilians Universität, Butenandtstrasse 5–13 (Haus F), D-81377 München, GermanyIn the title compound, C17H18O3, the two non-spiro C atoms of the cyclopropane ring bear a formyl and a phenyl substituent which are trans-oriented. In the crystal, molecules are linked by weak C—H...O and C—H...π contacts resulting in a three-dimensional supramolecular structure.http://scripts.iucr.org/cgi-bin/paper?S205698901600164Xcrystal structuresubstituted spiro-cyclopropanesweak C—H...O and C—H...π interactions
collection DOAJ
language English
format Article
sources DOAJ
author Saloua Chelli
Konstantin Troshin
Sami Lakhdar
Herbert Mayr
Peter Mayer
spellingShingle Saloua Chelli
Konstantin Troshin
Sami Lakhdar
Herbert Mayr
Peter Mayer
Crystal structure of (1S,2R)-6,6-dimethyl-4,8-dioxo-2-phenylspiro[2.5]octane-1-carbaldehyde
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
substituted spiro-cyclopropanes
weak C—H...O and C—H...π interactions
author_facet Saloua Chelli
Konstantin Troshin
Sami Lakhdar
Herbert Mayr
Peter Mayer
author_sort Saloua Chelli
title Crystal structure of (1S,2R)-6,6-dimethyl-4,8-dioxo-2-phenylspiro[2.5]octane-1-carbaldehyde
title_short Crystal structure of (1S,2R)-6,6-dimethyl-4,8-dioxo-2-phenylspiro[2.5]octane-1-carbaldehyde
title_full Crystal structure of (1S,2R)-6,6-dimethyl-4,8-dioxo-2-phenylspiro[2.5]octane-1-carbaldehyde
title_fullStr Crystal structure of (1S,2R)-6,6-dimethyl-4,8-dioxo-2-phenylspiro[2.5]octane-1-carbaldehyde
title_full_unstemmed Crystal structure of (1S,2R)-6,6-dimethyl-4,8-dioxo-2-phenylspiro[2.5]octane-1-carbaldehyde
title_sort crystal structure of (1s,2r)-6,6-dimethyl-4,8-dioxo-2-phenylspiro[2.5]octane-1-carbaldehyde
publisher International Union of Crystallography
series Acta Crystallographica Section E: Crystallographic Communications
issn 2056-9890
publishDate 2016-02-01
description In the title compound, C17H18O3, the two non-spiro C atoms of the cyclopropane ring bear a formyl and a phenyl substituent which are trans-oriented. In the crystal, molecules are linked by weak C—H...O and C—H...π contacts resulting in a three-dimensional supramolecular structure.
topic crystal structure
substituted spiro-cyclopropanes
weak C—H...O and C—H...π interactions
url http://scripts.iucr.org/cgi-bin/paper?S205698901600164X
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AT konstantintroshin crystalstructureof1s2r66dimethyl48dioxo2phenylspiro25octane1carbaldehyde
AT samilakhdar crystalstructureof1s2r66dimethyl48dioxo2phenylspiro25octane1carbaldehyde
AT herbertmayr crystalstructureof1s2r66dimethyl48dioxo2phenylspiro25octane1carbaldehyde
AT petermayer crystalstructureof1s2r66dimethyl48dioxo2phenylspiro25octane1carbaldehyde
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