Hidrogenação eletrocatalítica de substratos orgânicos utilizando eletrodos modificados poliméricos contendo partículas de Ni/Pd e Ni/Pt Electrocatalytic hydrogenation of organic substrates on polymer modified electrodes embedding Ni/Pd and Ni/Pt particles

<abstract language="eng">Novel modified electrodes bearing dispersed Pd and Pt particles have been prepared from poly (allyl ether of the p-benzenesulfonic acid) films with incorporated nickel particles making use of galvanic displacement reactions. The SEM analysis of the new modifi...

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Main Authors:	Fabiana L. S. Purgato, José R. Romero, Luisa M. Abrantes
Format:	Article
Language:	English
Published:	Sociedade Brasileira de Química 2009-01-01
Series:	Química Nova
Subjects:	modified electrode palladium and platinum particles complete aromatic hydrogenation
Online Access:	http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422009000500029

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spelling	doaj-9507df8f88fe4b65977cc80f34dbfc4b2020-11-25T02:30:53ZengSociedade Brasileira de QuímicaQuímica Nova0100-40421678-70642009-01-013251235123810.1590/S0100-40422009000500029Hidrogenação eletrocatalítica de substratos orgânicos utilizando eletrodos modificados poliméricos contendo partículas de Ni/Pd e Ni/Pt Electrocatalytic hydrogenation of organic substrates on polymer modified electrodes embedding Ni/Pd and Ni/Pt particlesFabiana L. S. PurgatoJosé R. RomeroLuisa M. Abrantes<abstract language="eng">Novel modified electrodes bearing dispersed Pd and Pt particles have been prepared from poly (allyl ether of the p-benzenesulfonic acid) films with incorporated nickel particles making use of galvanic displacement reactions. The SEM analysis of the new modified electrodes revealed efficient deposition of Pd but weak up-take of Pt. Electrocatalytic hydrogenation of several classes of organic substrates were carried out using the MEs Ni, Ni/Pd and Ni/Pt. The Ni/Pd ME showed to be the best of them for the hydrogenation of double, triple and carbonyl bonds. The complete hydrogenation of the aromatic rings for the well-adsorbed substrates acetophenone and benzophenone is noteworthy.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422009000500029modified electrodepalladium and platinum particlescomplete aromatic hydrogenation
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Fabiana L. S. Purgato José R. Romero Luisa M. Abrantes
spellingShingle	Fabiana L. S. Purgato José R. Romero Luisa M. Abrantes Hidrogenação eletrocatalítica de substratos orgânicos utilizando eletrodos modificados poliméricos contendo partículas de Ni/Pd e Ni/Pt Electrocatalytic hydrogenation of organic substrates on polymer modified electrodes embedding Ni/Pd and Ni/Pt particles Química Nova modified electrode palladium and platinum particles complete aromatic hydrogenation
author_facet	Fabiana L. S. Purgato José R. Romero Luisa M. Abrantes
author_sort	Fabiana L. S. Purgato
title	Hidrogenação eletrocatalítica de substratos orgânicos utilizando eletrodos modificados poliméricos contendo partículas de Ni/Pd e Ni/Pt Electrocatalytic hydrogenation of organic substrates on polymer modified electrodes embedding Ni/Pd and Ni/Pt particles
title_short	Hidrogenação eletrocatalítica de substratos orgânicos utilizando eletrodos modificados poliméricos contendo partículas de Ni/Pd e Ni/Pt Electrocatalytic hydrogenation of organic substrates on polymer modified electrodes embedding Ni/Pd and Ni/Pt particles
title_full	Hidrogenação eletrocatalítica de substratos orgânicos utilizando eletrodos modificados poliméricos contendo partículas de Ni/Pd e Ni/Pt Electrocatalytic hydrogenation of organic substrates on polymer modified electrodes embedding Ni/Pd and Ni/Pt particles
title_fullStr	Hidrogenação eletrocatalítica de substratos orgânicos utilizando eletrodos modificados poliméricos contendo partículas de Ni/Pd e Ni/Pt Electrocatalytic hydrogenation of organic substrates on polymer modified electrodes embedding Ni/Pd and Ni/Pt particles
title_full_unstemmed	Hidrogenação eletrocatalítica de substratos orgânicos utilizando eletrodos modificados poliméricos contendo partículas de Ni/Pd e Ni/Pt Electrocatalytic hydrogenation of organic substrates on polymer modified electrodes embedding Ni/Pd and Ni/Pt particles
title_sort	hidrogenação eletrocatalítica de substratos orgânicos utilizando eletrodos modificados poliméricos contendo partículas de ni/pd e ni/pt electrocatalytic hydrogenation of organic substrates on polymer modified electrodes embedding ni/pd and ni/pt particles
publisher	Sociedade Brasileira de Química
series	Química Nova
issn	0100-4042 1678-7064
publishDate	2009-01-01
description	<abstract language="eng">Novel modified electrodes bearing dispersed Pd and Pt particles have been prepared from poly (allyl ether of the p-benzenesulfonic acid) films with incorporated nickel particles making use of galvanic displacement reactions. The SEM analysis of the new modified electrodes revealed efficient deposition of Pd but weak up-take of Pt. Electrocatalytic hydrogenation of several classes of organic substrates were carried out using the MEs Ni, Ni/Pd and Ni/Pt. The Ni/Pd ME showed to be the best of them for the hydrogenation of double, triple and carbonyl bonds. The complete hydrogenation of the aromatic rings for the well-adsorbed substrates acetophenone and benzophenone is noteworthy.
topic	modified electrode palladium and platinum particles complete aromatic hydrogenation
url	http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422009000500029
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Hidrogenação eletrocatalítica de substratos orgânicos utilizando eletrodos modificados poliméricos contendo partículas de Ni/Pd e Ni/Pt Electrocatalytic hydrogenation of organic substrates on polymer modified electrodes embedding Ni/Pd and Ni/Pt particles

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