Hexnuclear Cadmium(II) Cluster Constructed from Tris(2-methylpyridyl)amine (TPA) and Azides

Hexnuclear Cadmium(II) Cluster Constructed from Tris(2-methylpyridyl)amine (TPA) and Azides

A novel rare hexa nuclear cadmium(II)–azide cluster, [Cd<sub>6</sub>(TPA)<sub>4</sub>(μ<sub>3</sub>-1,1,3-N<sub>3</sub>)<sub>4</sub>(μ<sub>2</sub>-1,1-N<sub>3</sub>)<sub>6</sub>](ClO<sub>4</sub&g...

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Bibliographic Details
Main Authors: Franz A. Mautner, Roland C. Fischer, Bailey R. Williams, Salah S. Massoud, Nahed M. H. Salem
Format: Article
Language:English
Published: MDPI AG 2020-04-01
Series:Crystals
Subjects:
cadmium
bridged azide
poylnuclear
cluster
X-ray
luminescence emission
Online Access:https://www.mdpi.com/2073-4352/10/4/317
Description
Summary:A novel rare hexa nuclear cadmium(II)–azide cluster, [Cd<sub>6</sub>(TPA)<sub>4</sub>(μ<sub>3</sub>-1,1,3-N<sub>3</sub>)<sub>4</sub>(μ<sub>2</sub>-1,1-N<sub>3</sub>)<sub>6</sub>](ClO<sub>4</sub>)<sub>2</sub>·2H<sub>2</sub>O (<b>1</b>) was isolated and structurally characterized, in which the azide ligands reveal μ-1,1,3- and μ-1,1-N<sub>3</sub> bridging modes.
ISSN:2073-4352

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