Enzymatic hydrolysis of poly(1,4-butylene 2,5-thiophenedicarboxylate) (PBTF) and poly(1,4-butylene 2,5-furandicarboxylate) (PBF) films: A comparison of mechanisms

Enzymatic hydrolysis of poly(1,4-butylene 2,5-thiophenedicarboxylate) (PBTF) and poly(1,4-butylene 2,5-furandicarboxylate) (PBF) films: A comparison of mechanisms

Enzymatic hydrolysis of poly(1,4-butylene 2,5-thiophenedicarboxylate) (PBTF) and poly(1,4-butylene 2,5-furandicarboxylate) (PBF) by Humicola insolens (HiC) and Thermobifida cellulosilytica (Cut) cutinases is investigated. For the first time, the different depolymerization mechanisms of PBTF (endo-wi...

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Main Authors: Matteo Gigli, Felice Quartinello, Michelina Soccio, Alessandro Pellis, Nadia Lotti, Georg M. Guebitz, Silvia Licoccia, Andrea Munari
Format: Article
Language:English
Published: Elsevier 2019-09-01
Series:Environment International
Online Access:http://www.sciencedirect.com/science/article/pii/S0160412019309213
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spelling doaj-94bc20e39c5341188c5a8a6f17f1ad862020-11-25T01:23:07ZengElsevierEnvironment International0160-41202019-09-01130Enzymatic hydrolysis of poly(1,4-butylene 2,5-thiophenedicarboxylate) (PBTF) and poly(1,4-butylene 2,5-furandicarboxylate) (PBF) films: A comparison of mechanismsMatteo Gigli0Felice Quartinello1Michelina Soccio2Alessandro Pellis3Nadia Lotti4Georg M. Guebitz5Silvia Licoccia6Andrea Munari7University of Roma Tor Vergata, Department of Chemical Science and Technologies, Via della Ricerca Scientifica 1, 00133 Roma, ItalyUniversity of Natural Resources and Life Sciences, Vienna, Department of Agrobiotechnology, Institute of Environmental Biotechnology, Konrad Lorenz Strasse 20, 3430 Tulln an der Donau, AustriaUniversity of Bologna, Department of Civil, Chemical, Environmental and Materials Engineering, Via Terracini 28, 40131 Bologna, ItalyUniversity of Natural Resources and Life Sciences, Vienna, Department of Agrobiotechnology, Institute of Environmental Biotechnology, Konrad Lorenz Strasse 20, 3430 Tulln an der Donau, Austria; University of York, Department of Chemistry, Green Chemistry Centre of Excellence, YO10 5DD Heslington, York, UK; Correspondence to: A. Pellis, University of York, Department of Chemistry, Green Chemistry Centre of Excellence, YO10 5DD Heslington, York, UK.University of Bologna, Department of Civil, Chemical, Environmental and Materials Engineering, Via Terracini 28, 40131 Bologna, Italy; Corresponding author.University of Natural Resources and Life Sciences, Vienna, Department of Agrobiotechnology, Institute of Environmental Biotechnology, Konrad Lorenz Strasse 20, 3430 Tulln an der Donau, Austria; Austrian Centre of Industrial Biotechnology, Konrad Lorenz Strasse 20, 3430 Tulln an der Donau, AustriaUniversity of Roma Tor Vergata, Department of Chemical Science and Technologies, Via della Ricerca Scientifica 1, 00133 Roma, ItalyUniversity of Bologna, Department of Civil, Chemical, Environmental and Materials Engineering, Via Terracini 28, 40131 Bologna, ItalyEnzymatic hydrolysis of poly(1,4-butylene 2,5-thiophenedicarboxylate) (PBTF) and poly(1,4-butylene 2,5-furandicarboxylate) (PBF) by Humicola insolens (HiC) and Thermobifida cellulosilytica (Cut) cutinases is investigated. For the first time, the different depolymerization mechanisms of PBTF (endo-wise scission) and PBF (exo-wise cleavage) has been unveiled and correlated to the chemical structure of the two polyesters. Keywords: Poly(1,4-butylene 2,5-thiophenedicarboxylate) (PBTF), Poly(1,4-butylene 2,5-furandicarboxylate) (PBF), Enzymatic hydrolysis, Endo/exo chain scission, Cutinases, Polyesters degradationhttp://www.sciencedirect.com/science/article/pii/S0160412019309213
collection DOAJ
language English
format Article
sources DOAJ
author Matteo Gigli
Felice Quartinello
Michelina Soccio
Alessandro Pellis
Nadia Lotti
Georg M. Guebitz
Silvia Licoccia
Andrea Munari
spellingShingle Matteo Gigli
Felice Quartinello
Michelina Soccio
Alessandro Pellis
Nadia Lotti
Georg M. Guebitz
Silvia Licoccia
Andrea Munari
Enzymatic hydrolysis of poly(1,4-butylene 2,5-thiophenedicarboxylate) (PBTF) and poly(1,4-butylene 2,5-furandicarboxylate) (PBF) films: A comparison of mechanisms
Environment International
author_facet Matteo Gigli
Felice Quartinello
Michelina Soccio
Alessandro Pellis
Nadia Lotti
Georg M. Guebitz
Silvia Licoccia
Andrea Munari
author_sort Matteo Gigli
title Enzymatic hydrolysis of poly(1,4-butylene 2,5-thiophenedicarboxylate) (PBTF) and poly(1,4-butylene 2,5-furandicarboxylate) (PBF) films: A comparison of mechanisms
title_short Enzymatic hydrolysis of poly(1,4-butylene 2,5-thiophenedicarboxylate) (PBTF) and poly(1,4-butylene 2,5-furandicarboxylate) (PBF) films: A comparison of mechanisms
title_full Enzymatic hydrolysis of poly(1,4-butylene 2,5-thiophenedicarboxylate) (PBTF) and poly(1,4-butylene 2,5-furandicarboxylate) (PBF) films: A comparison of mechanisms
title_fullStr Enzymatic hydrolysis of poly(1,4-butylene 2,5-thiophenedicarboxylate) (PBTF) and poly(1,4-butylene 2,5-furandicarboxylate) (PBF) films: A comparison of mechanisms
title_full_unstemmed Enzymatic hydrolysis of poly(1,4-butylene 2,5-thiophenedicarboxylate) (PBTF) and poly(1,4-butylene 2,5-furandicarboxylate) (PBF) films: A comparison of mechanisms
title_sort enzymatic hydrolysis of poly(1,4-butylene 2,5-thiophenedicarboxylate) (pbtf) and poly(1,4-butylene 2,5-furandicarboxylate) (pbf) films: a comparison of mechanisms
publisher Elsevier
series Environment International
issn 0160-4120
publishDate 2019-09-01
description Enzymatic hydrolysis of poly(1,4-butylene 2,5-thiophenedicarboxylate) (PBTF) and poly(1,4-butylene 2,5-furandicarboxylate) (PBF) by Humicola insolens (HiC) and Thermobifida cellulosilytica (Cut) cutinases is investigated. For the first time, the different depolymerization mechanisms of PBTF (endo-wise scission) and PBF (exo-wise cleavage) has been unveiled and correlated to the chemical structure of the two polyesters. Keywords: Poly(1,4-butylene 2,5-thiophenedicarboxylate) (PBTF), Poly(1,4-butylene 2,5-furandicarboxylate) (PBF), Enzymatic hydrolysis, Endo/exo chain scission, Cutinases, Polyesters degradation
url http://www.sciencedirect.com/science/article/pii/S0160412019309213
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