4-Aminopyridinium trans-diaquadioxalatochromate(III) monohydrate

4-Aminopyridinium trans-diaquadioxalatochromate(III) monohydrate

In the non-centrosymmetric structure of the title compound, (C5H7N2)[Cr(C2O4)2(H2O)2]·H2O, the CrIII ion has a slightly distorted octahedral coordination environment defined by two chelating oxalato ligands in equatorial positions and two water molecules in axial positions. An extensive...

Full description

Bibliographic Details
Main Authors: Ichraf Chérif, Jawher Abdelhak, Mohamed Faouzi Zid, Ahmed Driss
Format: Article
Language:English
Published: International Union of Crystallography 2011-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811044837
id doaj-949da4cce88d412a9b5c2e241fcaba98
record_format Article
spelling doaj-949da4cce88d412a9b5c2e241fcaba982020-11-25T00:49:56ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-12-016712m1648m164910.1107/S16005368110448374-Aminopyridinium trans-diaquadioxalatochromate(III) monohydrateIchraf ChérifJawher AbdelhakMohamed Faouzi ZidAhmed DrissIn the non-centrosymmetric structure of the title compound, (C5H7N2)[Cr(C2O4)2(H2O)2]·H2O, the CrIII ion has a slightly distorted octahedral coordination environment defined by two chelating oxalato ligands in equatorial positions and two water molecules in axial positions. An extensive three-dimensional network of hydrogen bonds involving all the water molecules, the 4-aminopyridinium cation and some of the oxalate O atoms contributes to the stabilization of the structure. π–π interactions between adjacent pyridine rings provide additional stability of the crystal packing, with a closest distance between pyridine mean planes of 3.613 (1) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536811044837
collection DOAJ
language English
format Article
sources DOAJ
author Ichraf Chérif
Jawher Abdelhak
Mohamed Faouzi Zid
Ahmed Driss
spellingShingle Ichraf Chérif
Jawher Abdelhak
Mohamed Faouzi Zid
Ahmed Driss
4-Aminopyridinium trans-diaquadioxalatochromate(III) monohydrate
Acta Crystallographica Section E
author_facet Ichraf Chérif
Jawher Abdelhak
Mohamed Faouzi Zid
Ahmed Driss
author_sort Ichraf Chérif
title 4-Aminopyridinium trans-diaquadioxalatochromate(III) monohydrate
title_short 4-Aminopyridinium trans-diaquadioxalatochromate(III) monohydrate
title_full 4-Aminopyridinium trans-diaquadioxalatochromate(III) monohydrate
title_fullStr 4-Aminopyridinium trans-diaquadioxalatochromate(III) monohydrate
title_full_unstemmed 4-Aminopyridinium trans-diaquadioxalatochromate(III) monohydrate
title_sort 4-aminopyridinium trans-diaquadioxalatochromate(iii) monohydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-12-01
description In the non-centrosymmetric structure of the title compound, (C5H7N2)[Cr(C2O4)2(H2O)2]·H2O, the CrIII ion has a slightly distorted octahedral coordination environment defined by two chelating oxalato ligands in equatorial positions and two water molecules in axial positions. An extensive three-dimensional network of hydrogen bonds involving all the water molecules, the 4-aminopyridinium cation and some of the oxalate O atoms contributes to the stabilization of the structure. π–π interactions between adjacent pyridine rings provide additional stability of the crystal packing, with a closest distance between pyridine mean planes of 3.613 (1) Å.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811044837
work_keys_str_mv AT ichrafchamp233rif 4aminopyridiniumtransdiaquadioxalatochromateiiimonohydrate
AT jawherabdelhak 4aminopyridiniumtransdiaquadioxalatochromateiiimonohydrate
AT mohamedfaouzizid 4aminopyridiniumtransdiaquadioxalatochromateiiimonohydrate
AT ahmeddriss 4aminopyridiniumtransdiaquadioxalatochromateiiimonohydrate
_version_ 1725250232334155776

Similar Items