N,N-Bis(diphenylthiophosphinoyl)-4-ethylaniline

N,N-Bis(diphenylthiophosphinoyl)-4-ethylaniline

The title compound, C32H29NP2S2, has two molecules in the asymmetric unit, with an r.m.s. difference of 0.218 Å in their best-fit overlay. Both molecules have a slightly distorted trigonal–planar N atom, bonded to two PV atoms and a C atom of the 4-ethylpheny...

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Bibliographic Details
Main Authors: Peter A. Ajibade, Damian C. Onwudiwe, Bernard Omondi
Format: Article
Language:English
Published: International Union of Crystallography 2012-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812048416
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spelling doaj-9422f8eb4ae94f99832301413b2e89372020-11-25T02:30:48ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-12-016812o3491o349210.1107/S1600536812048416N,N-Bis(diphenylthiophosphinoyl)-4-ethylanilinePeter A. AjibadeDamian C. OnwudiweBernard OmondiThe title compound, C32H29NP2S2, has two molecules in the asymmetric unit, with an r.m.s. difference of 0.218 Å in their best-fit overlay. Both molecules have a slightly distorted trigonal–planar N atom, bonded to two PV atoms and a C atom of the 4-ethylphenyl unit. The P—N—P angles of 126.34 (11) and 125.98 (11)° are larger than the four C—N—P bond angles. The two S atoms are trans to one another with respect to the P—N—P angle. The crystal structure features C—H...π interactions. The methyl group in one of the molecules is disordered over two sets of sites, with occupancies of 0.518 (6) and 0.482 (6).http://scripts.iucr.org/cgi-bin/paper?S1600536812048416
collection DOAJ
language English
format Article
sources DOAJ
author Peter A. Ajibade
Damian C. Onwudiwe
Bernard Omondi
spellingShingle Peter A. Ajibade
Damian C. Onwudiwe
Bernard Omondi
N,N-Bis(diphenylthiophosphinoyl)-4-ethylaniline
Acta Crystallographica Section E
author_facet Peter A. Ajibade
Damian C. Onwudiwe
Bernard Omondi
author_sort Peter A. Ajibade
title N,N-Bis(diphenylthiophosphinoyl)-4-ethylaniline
title_short N,N-Bis(diphenylthiophosphinoyl)-4-ethylaniline
title_full N,N-Bis(diphenylthiophosphinoyl)-4-ethylaniline
title_fullStr N,N-Bis(diphenylthiophosphinoyl)-4-ethylaniline
title_full_unstemmed N,N-Bis(diphenylthiophosphinoyl)-4-ethylaniline
title_sort n,n-bis(diphenylthiophosphinoyl)-4-ethylaniline
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-12-01
description The title compound, C32H29NP2S2, has two molecules in the asymmetric unit, with an r.m.s. difference of 0.218 Å in their best-fit overlay. Both molecules have a slightly distorted trigonal–planar N atom, bonded to two PV atoms and a C atom of the 4-ethylphenyl unit. The P—N—P angles of 126.34 (11) and 125.98 (11)° are larger than the four C—N—P bond angles. The two S atoms are trans to one another with respect to the P—N—P angle. The crystal structure features C—H...π interactions. The methyl group in one of the molecules is disordered over two sets of sites, with occupancies of 0.518 (6) and 0.482 (6).
url http://scripts.iucr.org/cgi-bin/paper?S1600536812048416
work_keys_str_mv AT peteraajibade nnbisdiphenylthiophosphinoyl4ethylaniline
AT damianconwudiwe nnbisdiphenylthiophosphinoyl4ethylaniline
AT bernardomondi nnbisdiphenylthiophosphinoyl4ethylaniline
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