(Acetato-κ2O,O′)(acetato-κO)bis(2-amino-3-methylpyridine-κN1)cobalt(II)

(Acetato-κ2O,O′)(acetato-κO)bis(2-amino-3-methylpyridine-κN1)cobalt(II)

In the title compound, [Co(CH3COO)2(C6H8N2)2], the CoII ion is five-coordinated by two pyridine N atoms from two 2-amino-3-methylpyridine ligands, two O atoms from one acetate ion and one O atom from another acetate ion in a distorted trigonal–bipyramidal geometry. The pyridine rings a...

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Main Authors: Azadeh Tadjarodi, Keyvan Bijanzad, Behrouz Notash
Format: Article
Language:English
Published: International Union of Crystallography 2012-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812038664
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spelling doaj-940b71ff4cb1421a85e879c140066e002020-11-25T02:30:47ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-10-016810m1260m126110.1107/S1600536812038664(Acetato-κ2O,O′)(acetato-κO)bis(2-amino-3-methylpyridine-κN1)cobalt(II)Azadeh TadjarodiKeyvan BijanzadBehrouz NotashIn the title compound, [Co(CH3COO)2(C6H8N2)2], the CoII ion is five-coordinated by two pyridine N atoms from two 2-amino-3-methylpyridine ligands, two O atoms from one acetate ion and one O atom from another acetate ion in a distorted trigonal–bipyramidal geometry. The pyridine rings are nearly perpendicular to each other [dihedral angle = 84.49 (16)°]. The crystal packing is stabilized by intramolecular and intermolecular N—H...O hydrogen-bonding interactions.http://scripts.iucr.org/cgi-bin/paper?S1600536812038664
collection DOAJ
language English
format Article
sources DOAJ
author Azadeh Tadjarodi
Keyvan Bijanzad
Behrouz Notash
spellingShingle Azadeh Tadjarodi
Keyvan Bijanzad
Behrouz Notash
(Acetato-κ2O,O′)(acetato-κO)bis(2-amino-3-methylpyridine-κN1)cobalt(II)
Acta Crystallographica Section E
author_facet Azadeh Tadjarodi
Keyvan Bijanzad
Behrouz Notash
author_sort Azadeh Tadjarodi
title (Acetato-κ2O,O′)(acetato-κO)bis(2-amino-3-methylpyridine-κN1)cobalt(II)
title_short (Acetato-κ2O,O′)(acetato-κO)bis(2-amino-3-methylpyridine-κN1)cobalt(II)
title_full (Acetato-κ2O,O′)(acetato-κO)bis(2-amino-3-methylpyridine-κN1)cobalt(II)
title_fullStr (Acetato-κ2O,O′)(acetato-κO)bis(2-amino-3-methylpyridine-κN1)cobalt(II)
title_full_unstemmed (Acetato-κ2O,O′)(acetato-κO)bis(2-amino-3-methylpyridine-κN1)cobalt(II)
title_sort (acetato-κ2o,o′)(acetato-κo)bis(2-amino-3-methylpyridine-κn1)cobalt(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-10-01
description In the title compound, [Co(CH3COO)2(C6H8N2)2], the CoII ion is five-coordinated by two pyridine N atoms from two 2-amino-3-methylpyridine ligands, two O atoms from one acetate ion and one O atom from another acetate ion in a distorted trigonal–bipyramidal geometry. The pyridine rings are nearly perpendicular to each other [dihedral angle = 84.49 (16)°]. The crystal packing is stabilized by intramolecular and intermolecular N—H...O hydrogen-bonding interactions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812038664
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AT keyvanbijanzad acetatoamp9542ooamp8242acetatoamp954obis2amino3methylpyridineamp954n1cobaltii
AT behrouznotash acetatoamp9542ooamp8242acetatoamp954obis2amino3methylpyridineamp954n1cobaltii
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