Cs5Sn9(OH)·4NH3

Cs5Sn9(OH)·4NH3

The title compound, pentacaesium nonastannide hydroxide tetraammonia, crystallized from a solution of CsSnBi in liquid ammonia. The Sn94− unit forms a monocapped quadratic antiprism. The hydroxide ion is surrounded by five caesium cations, which form a distorted quadratic pyramidal polyhedron. A thr...

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Main Authors: Ute Friedrich, Nikolaus Korber
Format: Article
Language:English
Published: International Union of Crystallography 2014-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814011817
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spelling doaj-93ef8e79d49048e4b4c8d6948373bc122020-11-25T02:40:10ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-06-01706i29i2910.1107/S1600536814011817ru2058Cs5Sn9(OH)·4NH3Ute Friedrich0Nikolaus Korber1Institut für Anorganische Chemie, Universität Regensburg, Universitätsstrasse 31, 93053 Regensburg, GermanyInstitut für Anorganische Chemie, Universität Regensburg, Universitätsstrasse 31, 93053 Regensburg, GermanyThe title compound, pentacaesium nonastannide hydroxide tetraammonia, crystallized from a solution of CsSnBi in liquid ammonia. The Sn94− unit forms a monocapped quadratic antiprism. The hydroxide ion is surrounded by five caesium cations, which form a distorted quadratic pyramidal polyhedron. A three-dimensional network is formed by Cs—Sn [3.8881 (7) Å to 4.5284 (7) Å] and Cs—NH3 [3.276 (7)–3.636 (7) Å] contacts.http://scripts.iucr.org/cgi-bin/paper?S1600536814011817
collection DOAJ
language English
format Article
sources DOAJ
author Ute Friedrich
Nikolaus Korber
spellingShingle Ute Friedrich
Nikolaus Korber
Cs5Sn9(OH)·4NH3
Acta Crystallographica Section E
author_facet Ute Friedrich
Nikolaus Korber
author_sort Ute Friedrich
title Cs5Sn9(OH)·4NH3
title_short Cs5Sn9(OH)·4NH3
title_full Cs5Sn9(OH)·4NH3
title_fullStr Cs5Sn9(OH)·4NH3
title_full_unstemmed Cs5Sn9(OH)·4NH3
title_sort cs5sn9(oh)·4nh3
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2014-06-01
description The title compound, pentacaesium nonastannide hydroxide tetraammonia, crystallized from a solution of CsSnBi in liquid ammonia. The Sn94− unit forms a monocapped quadratic antiprism. The hydroxide ion is surrounded by five caesium cations, which form a distorted quadratic pyramidal polyhedron. A three-dimensional network is formed by Cs—Sn [3.8881 (7) Å to 4.5284 (7) Å] and Cs—NH3 [3.276 (7)–3.636 (7) Å] contacts.
url http://scripts.iucr.org/cgi-bin/paper?S1600536814011817
work_keys_str_mv AT utefriedrich cs5sn9oh4nh3
AT nikolauskorber cs5sn9oh4nh3
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