Preparation and Properties of Iminodiacetic Acid Chelate Fiber

The iminodiacetic acid chelate fiber(IDACF) which has a property of selective adsorption, was fabricated by amination and carboxylation using chloramethylated polypropylene grafted styrene fiber as raw material. Orthogonal experiment was adopted to study the effect of temperature, time, liquor ratio...

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Bibliographic Details
Main Authors: QIAN Jin-xin, LI Ming-yu, FENG Chang-gen
Format: Article
Language:zho
Published: Journal of Materials Engineering 2016-07-01
Series:Journal of Materials Engineering
Subjects:
Online Access:http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2016.07.010
Description
Summary:The iminodiacetic acid chelate fiber(IDACF) which has a property of selective adsorption, was fabricated by amination and carboxylation using chloramethylated polypropylene grafted styrene fiber as raw material. Orthogonal experiment was adopted to study the effect of temperature, time, liquor ratio and the amount of chloroacetic acid on carboxylation reaction. The maximum adsorption capacity of iminodiacetic acid chelate fiber to Cu<sup>2+</sup> is 65.54mg&#183;g<sup>-1</sup>, which is 10.52 times of that of Fe<sup>3+</sup>. Elementary analysis(EA), Fourier transform infrared spectrum(FT-IR), scanning electron microscopy(SEM) and thermogrametry(TG) were used to characterize the structure and the properties of the iminodiacetic acid chelate fiber. The results show that iminodiacetic acid has been transformed to the raw fiber successfully after amination and carboxymethylation, and IDACF has good thermal stability.
ISSN:1001-4381
1001-4381