5-(4-Bromophenyl)-1,2,3,4-tetrahydrobenzo[a]phenanthridine
The title compound, C23H18BrN, was synthesized by the reaction of 4-bromobenzaldehyde, naphthalen-2-amine and cyclohexanone in tetrahydrofuran, catalyzed by iodine. The saturated six-membered ring adopts a half-chair conformation, and the four vicinal rings form a helical conformation, which results...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809013713 |
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doaj-930826d4529748c49c235afba050ebbe2020-11-24T21:22:14ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-05-01655o1074o107410.1107/S16005368090137135-(4-Bromophenyl)-1,2,3,4-tetrahydrobenzo[a]phenanthridineLing SuAi-Ling ZhangHeng-Shen XieThe title compound, C23H18BrN, was synthesized by the reaction of 4-bromobenzaldehyde, naphthalen-2-amine and cyclohexanone in tetrahydrofuran, catalyzed by iodine. The saturated six-membered ring adopts a half-chair conformation, and the four vicinal rings form a helical conformation, which results in a significant deviation from planarity for the pyridine ring. In the crystal, a weak C—H...π interaction occurs, leading to inversion dimers. http://scripts.iucr.org/cgi-bin/paper?S1600536809013713 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Ling Su Ai-Ling Zhang Heng-Shen Xie |
| spellingShingle |
Ling Su Ai-Ling Zhang Heng-Shen Xie 5-(4-Bromophenyl)-1,2,3,4-tetrahydrobenzo[a]phenanthridine Acta Crystallographica Section E |
| author_facet |
Ling Su Ai-Ling Zhang Heng-Shen Xie |
| author_sort |
Ling Su |
| title |
5-(4-Bromophenyl)-1,2,3,4-tetrahydrobenzo[a]phenanthridine |
| title_short |
5-(4-Bromophenyl)-1,2,3,4-tetrahydrobenzo[a]phenanthridine |
| title_full |
5-(4-Bromophenyl)-1,2,3,4-tetrahydrobenzo[a]phenanthridine |
| title_fullStr |
5-(4-Bromophenyl)-1,2,3,4-tetrahydrobenzo[a]phenanthridine |
| title_full_unstemmed |
5-(4-Bromophenyl)-1,2,3,4-tetrahydrobenzo[a]phenanthridine |
| title_sort |
5-(4-bromophenyl)-1,2,3,4-tetrahydrobenzo[a]phenanthridine |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2009-05-01 |
| description |
The title compound, C23H18BrN, was synthesized by the reaction of 4-bromobenzaldehyde, naphthalen-2-amine and cyclohexanone in tetrahydrofuran, catalyzed by iodine. The saturated six-membered ring adopts a half-chair conformation, and the four vicinal rings form a helical conformation, which results in a significant deviation from planarity for the pyridine ring. In the crystal, a weak C—H...π interaction occurs, leading to inversion dimers. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536809013713 |
| work_keys_str_mv |
AT lingsu 54bromophenyl1234tetrahydrobenzoaphenanthridine AT ailingzhang 54bromophenyl1234tetrahydrobenzoaphenanthridine AT hengshenxie 54bromophenyl1234tetrahydrobenzoaphenanthridine |
| _version_ |
1725996766541643776 |