5-(4-Bromophenyl)-1,2,3,4-tetrahydrobenzo[a]phenanthridine
The title compound, C23H18BrN, was synthesized by the reaction of 4-bromobenzaldehyde, naphthalen-2-amine and cyclohexanone in tetrahydrofuran, catalyzed by iodine. The saturated six-membered ring adopts a half-chair conformation, and the four vicinal rings form a helical conformation, which results...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809013713 |
| Summary: | The title compound, C23H18BrN, was synthesized by the reaction of 4-bromobenzaldehyde, naphthalen-2-amine and cyclohexanone in tetrahydrofuran, catalyzed by iodine. The saturated six-membered ring adopts a half-chair conformation, and the four vicinal rings form a helical conformation, which results in a significant deviation from planarity for the pyridine ring. In the crystal, a weak C—H...π interaction occurs, leading to inversion dimers. |
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| ISSN: | 1600-5368 |