Exraction and separation of CERIUM(IV)/FLUORINE in fluoride-bearing cerium sulfate solution with fluoride coordination agent
In this paper the extraction and separation of cerium/fluorine in fluoride-bearing cerium sulfate solution with fluoride coordination agent has been studied. The UV-vis spectra suggest that Zr<sup>6+</sup> and Al<sup>3+</sup> can scrub the F<sup>-</sup> from [CeF&...
Main Authors: | , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Croatian Metallurgical Society
2014-07-01
|
Series: | Metalurgija |
Subjects: | |
Online Access: | http://hrcak.srce.hr/file/176684 |
id |
doaj-93040cc7f63e4c6e83d7d86fffc636ac |
---|---|
record_format |
Article |
spelling |
doaj-93040cc7f63e4c6e83d7d86fffc636ac2020-11-24T23:44:24ZengCroatian Metallurgical SocietyMetalurgija0543-58461334-25762014-07-01533320322Exraction and separation of CERIUM(IV)/FLUORINE in fluoride-bearing cerium sulfate solution with fluoride coordination agent Y. LiJ. G. HeX. X. XueH. Q. RuX. W. HuangH. YangIn this paper the extraction and separation of cerium/fluorine in fluoride-bearing cerium sulfate solution with fluoride coordination agent has been studied. The UV-vis spectra suggest that Zr<sup>6+</sup> and Al<sup>3+</sup> can scrub the F<sup>-</sup> from [CeF<sub>2</sub>] <sup>2+</sup> complex. The separation and conductivity studies show that aluminum salt is the most suitable fluoride coordination agent, and an ion-exchange reaction is involved between Ce<sup>4+</sup>/ [CeF<sub>2</sub>] <sup>2+</sup> and hydrogen ion. http://hrcak.srce.hr/file/176684fluorineceriumseparationfluoride coordination agent |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Y. Li J. G. He X. X. Xue H. Q. Ru X. W. Huang H. Yang |
spellingShingle |
Y. Li J. G. He X. X. Xue H. Q. Ru X. W. Huang H. Yang Exraction and separation of CERIUM(IV)/FLUORINE in fluoride-bearing cerium sulfate solution with fluoride coordination agent Metalurgija fluorine cerium separation fluoride coordination agent |
author_facet |
Y. Li J. G. He X. X. Xue H. Q. Ru X. W. Huang H. Yang |
author_sort |
Y. Li |
title |
Exraction and separation of CERIUM(IV)/FLUORINE in fluoride-bearing cerium sulfate solution with fluoride coordination agent |
title_short |
Exraction and separation of CERIUM(IV)/FLUORINE in fluoride-bearing cerium sulfate solution with fluoride coordination agent |
title_full |
Exraction and separation of CERIUM(IV)/FLUORINE in fluoride-bearing cerium sulfate solution with fluoride coordination agent |
title_fullStr |
Exraction and separation of CERIUM(IV)/FLUORINE in fluoride-bearing cerium sulfate solution with fluoride coordination agent |
title_full_unstemmed |
Exraction and separation of CERIUM(IV)/FLUORINE in fluoride-bearing cerium sulfate solution with fluoride coordination agent |
title_sort |
exraction and separation of cerium(iv)/fluorine in fluoride-bearing cerium sulfate solution with fluoride coordination agent |
publisher |
Croatian Metallurgical Society |
series |
Metalurgija |
issn |
0543-5846 1334-2576 |
publishDate |
2014-07-01 |
description |
In this paper the extraction and separation of cerium/fluorine in fluoride-bearing cerium sulfate solution with fluoride coordination agent has been studied. The UV-vis spectra suggest that Zr<sup>6+</sup> and Al<sup>3+</sup> can scrub the F<sup>-</sup> from [CeF<sub>2</sub>] <sup>2+</sup> complex. The separation and conductivity studies show that aluminum salt is the most suitable fluoride coordination agent, and an ion-exchange reaction is involved between Ce<sup>4+</sup>/ [CeF<sub>2</sub>] <sup>2+</sup> and hydrogen ion. |
topic |
fluorine cerium separation fluoride coordination agent |
url |
http://hrcak.srce.hr/file/176684 |
work_keys_str_mv |
AT yli exractionandseparationofceriumivfluorineinfluoridebearingceriumsulfatesolutionwithfluoridecoordinationagent AT jghe exractionandseparationofceriumivfluorineinfluoridebearingceriumsulfatesolutionwithfluoridecoordinationagent AT xxxue exractionandseparationofceriumivfluorineinfluoridebearingceriumsulfatesolutionwithfluoridecoordinationagent AT hqru exractionandseparationofceriumivfluorineinfluoridebearingceriumsulfatesolutionwithfluoridecoordinationagent AT xwhuang exractionandseparationofceriumivfluorineinfluoridebearingceriumsulfatesolutionwithfluoridecoordinationagent AT hyang exractionandseparationofceriumivfluorineinfluoridebearingceriumsulfatesolutionwithfluoridecoordinationagent |
_version_ |
1725498745282363392 |