5,7,12,14-Tetrahydro-5,14:7,12-bis([1,2]benzeno)pentacene-6,13-diol dimethylformamide disolvate

5,7,12,14-Tetrahydro-5,14:7,12-bis([1,2]benzeno)pentacene-6,13-diol dimethylformamide disolvate

The crystal lattice of the title compound, C34H22O2·2C3H7NO, at 173 K has monoclinic (P21/n) symmetry. Molecules are located on crystallographic centers of symmetry and have approximate non-crystallographic mmm symmetry, indicating that in solution the chemical and spectroscopic behavior would be th...

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Main Authors: Mohammad Nozari, Manpreet Kaur, Jerry P. Jasinski, Anthony W. Addison, Ahmad Arabi Shamsabadi, Masoud Soroush
Format: Article
Language:English
Published: International Union of Crystallography 2016-07-01
Series:IUCrData
Subjects:
crystal structure
iptycene
pentiptycene
polymers of intrinsic microporosity (PIM)
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314616011305
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spelling doaj-92b66fed1bc14124a379522ddbdb26622020-11-24T21:03:12ZengInternational Union of CrystallographyIUCrData2414-31462016-07-0117x16113010.1107/S2414314616011305zl40105,7,12,14-Tetrahydro-5,14:7,12-bis([1,2]benzeno)pentacene-6,13-diol dimethylformamide disolvateMohammad Nozari0Manpreet Kaur1Jerry P. Jasinski2Anthony W. Addison3Ahmad Arabi Shamsabadi4Masoud Soroush5Department of Chemistry, Drexel University, 3141 Chestnut St, Philadelphia, PA 19104, USADepartment of Chemistry, Keene State College, 229 Main Street, Keene, NH 03435-2001, USADepartment of Chemistry, Keene State College, 229 Main Street, Keene, NH 03435-2001, USADepartment of Chemistry, Drexel University, 3141 Chestnut St, Philadelphia, PA 19104, USADepartment of Chemical and Biological Engineering, Drexel University, 3141 Chestnut St, Philadelphia, PA 19104, USADepartment of Chemical and Biological Engineering, Drexel University, 3141 Chestnut St, Philadelphia, PA 19104, USAThe crystal lattice of the title compound, C34H22O2·2C3H7NO, at 173 K has monoclinic (P21/n) symmetry. Molecules are located on crystallographic centers of symmetry and have approximate non-crystallographic mmm symmetry, indicating that in solution the chemical and spectroscopic behavior would be that of a D2h molecule. The compound has applications in gas-separation membranes fabricated from polymers of intrinsic microporosity (PIM). The compound is the product of reduction of the corresponding quinone by Na2S2O4 in DMF/NaHCO3.http://scripts.iucr.org/cgi-bin/paper?S2414314616011305crystal structureiptycenepentiptycenepolymers of intrinsic microporosity (PIM)
collection DOAJ
language English
format Article
sources DOAJ
author Mohammad Nozari
Manpreet Kaur
Jerry P. Jasinski
Anthony W. Addison
Ahmad Arabi Shamsabadi
Masoud Soroush
spellingShingle Mohammad Nozari
Manpreet Kaur
Jerry P. Jasinski
Anthony W. Addison
Ahmad Arabi Shamsabadi
Masoud Soroush
5,7,12,14-Tetrahydro-5,14:7,12-bis([1,2]benzeno)pentacene-6,13-diol dimethylformamide disolvate
IUCrData
crystal structure
iptycene
pentiptycene
polymers of intrinsic microporosity (PIM)
author_facet Mohammad Nozari
Manpreet Kaur
Jerry P. Jasinski
Anthony W. Addison
Ahmad Arabi Shamsabadi
Masoud Soroush
author_sort Mohammad Nozari
title 5,7,12,14-Tetrahydro-5,14:7,12-bis([1,2]benzeno)pentacene-6,13-diol dimethylformamide disolvate
title_short 5,7,12,14-Tetrahydro-5,14:7,12-bis([1,2]benzeno)pentacene-6,13-diol dimethylformamide disolvate
title_full 5,7,12,14-Tetrahydro-5,14:7,12-bis([1,2]benzeno)pentacene-6,13-diol dimethylformamide disolvate
title_fullStr 5,7,12,14-Tetrahydro-5,14:7,12-bis([1,2]benzeno)pentacene-6,13-diol dimethylformamide disolvate
title_full_unstemmed 5,7,12,14-Tetrahydro-5,14:7,12-bis([1,2]benzeno)pentacene-6,13-diol dimethylformamide disolvate
title_sort 5,7,12,14-tetrahydro-5,14:7,12-bis([1,2]benzeno)pentacene-6,13-diol dimethylformamide disolvate
publisher International Union of Crystallography
series IUCrData
issn 2414-3146
publishDate 2016-07-01
description The crystal lattice of the title compound, C34H22O2·2C3H7NO, at 173 K has monoclinic (P21/n) symmetry. Molecules are located on crystallographic centers of symmetry and have approximate non-crystallographic mmm symmetry, indicating that in solution the chemical and spectroscopic behavior would be that of a D2h molecule. The compound has applications in gas-separation membranes fabricated from polymers of intrinsic microporosity (PIM). The compound is the product of reduction of the corresponding quinone by Na2S2O4 in DMF/NaHCO3.
topic crystal structure
iptycene
pentiptycene
polymers of intrinsic microporosity (PIM)
url http://scripts.iucr.org/cgi-bin/paper?S2414314616011305
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AT manpreetkaur 571214tetrahydro514712bis12benzenopentacene613dioldimethylformamidedisolvate
AT jerrypjasinski 571214tetrahydro514712bis12benzenopentacene613dioldimethylformamidedisolvate
AT anthonywaddison 571214tetrahydro514712bis12benzenopentacene613dioldimethylformamidedisolvate
AT ahmadarabishamsabadi 571214tetrahydro514712bis12benzenopentacene613dioldimethylformamidedisolvate
AT masoudsoroush 571214tetrahydro514712bis12benzenopentacene613dioldimethylformamidedisolvate
_version_ 1716773760026017792

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