Bis{N-ethyl-2-[3-(hydroxyimino-κN)butan-2-ylidene]hydrazinecarbothioamide-κ2N2,S}nickel(II) dichloride

Bis{N-ethyl-2-[3-(hydroxyimino-κN)butan-2-ylidene]hydrazinecarbothioamide-κ2N2,S}nickel(II) dichloride

In the title complex, [Ni(C7H14N4OS)2]Cl2, the NiII ion is six-coordinated in a distorted octahedral geometry by four N atoms from the two imine and two oxime groups, and two S atoms from the thione groups. Two chloride ions complete the asymmetric unit. In the crystal, molecules are linked through...

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Bibliographic Details
Main Authors: Halema Shaban Abduelftah, Amna Qasem Ali, Naser Eltaher Eltayeb, Siang Guan Teoh, Hoong-Kun Fun
Format: Article
Language:English
Published: International Union of Crystallography 2012-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811055383
Description
Summary:In the title complex, [Ni(C7H14N4OS)2]Cl2, the NiII ion is six-coordinated in a distorted octahedral geometry by four N atoms from the two imine and two oxime groups, and two S atoms from the thione groups. Two chloride ions complete the asymmetric unit. In the crystal, molecules are linked through N—H...Cl and O—H...Cl hydrogen bonds into an infinite chain propagating along [101].
ISSN:1600-5368

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