A new hybrid Dawson-type molybdenum arsenate derivative: (H2bpy)3[As2Mo18O62] (bpy = 4,4′-bipyridine)

A new hybrid Dawson-type molybdenum arsenate derivative: (H2bpy)3[As2Mo18O62] (bpy = 4,4′-bipyridine)

The title compound, tris(4,4′-bipyridinium) diarsenooctadecamolybdate(VI), (C10H10N2)3[As2Mo18O62], featuring protonated bipyridine molecules and a classical Dawson-type polyoxo-anion, has been synthesized under hydrothermal conditions. The polyoxoanions are linked together via the bip...

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Main Authors: Ji-qing Xu, Li Kong, Hai-hui Yu, Xiao Zhang
Format: Article
Language:English
Published: International Union of Crystallography 2009-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809050260
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spelling doaj-927a722e007a42488e0e4f4465264bc52020-11-25T02:14:20ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-12-016512m1698m169910.1107/S1600536809050260A new hybrid Dawson-type molybdenum arsenate derivative: (H2bpy)3[As2Mo18O62] (bpy = 4,4′-bipyridine)Ji-qing XuLi KongHai-hui YuXiao ZhangThe title compound, tris(4,4′-bipyridinium) diarsenooctadecamolybdate(VI), (C10H10N2)3[As2Mo18O62], featuring protonated bipyridine molecules and a classical Dawson-type polyoxo-anion, has been synthesized under hydrothermal conditions. The polyoxoanions are linked together via the bipyridyl cations, acting as hydrogen-bond donors, generating a two-dimensional supramolecular network. The asymmetric unit contains 1.5 4,4′-bipyridinium (H2bpy) units, with an inversion centre in the central bond of the second H2bpy unit. The site symmetry of the anion is overline{1}. http://scripts.iucr.org/cgi-bin/paper?S1600536809050260
collection DOAJ
language English
format Article
sources DOAJ
author Ji-qing Xu
Li Kong
Hai-hui Yu
Xiao Zhang
spellingShingle Ji-qing Xu
Li Kong
Hai-hui Yu
Xiao Zhang
A new hybrid Dawson-type molybdenum arsenate derivative: (H2bpy)3[As2Mo18O62] (bpy = 4,4′-bipyridine)
Acta Crystallographica Section E
author_facet Ji-qing Xu
Li Kong
Hai-hui Yu
Xiao Zhang
author_sort Ji-qing Xu
title A new hybrid Dawson-type molybdenum arsenate derivative: (H2bpy)3[As2Mo18O62] (bpy = 4,4′-bipyridine)
title_short A new hybrid Dawson-type molybdenum arsenate derivative: (H2bpy)3[As2Mo18O62] (bpy = 4,4′-bipyridine)
title_full A new hybrid Dawson-type molybdenum arsenate derivative: (H2bpy)3[As2Mo18O62] (bpy = 4,4′-bipyridine)
title_fullStr A new hybrid Dawson-type molybdenum arsenate derivative: (H2bpy)3[As2Mo18O62] (bpy = 4,4′-bipyridine)
title_full_unstemmed A new hybrid Dawson-type molybdenum arsenate derivative: (H2bpy)3[As2Mo18O62] (bpy = 4,4′-bipyridine)
title_sort new hybrid dawson-type molybdenum arsenate derivative: (h2bpy)3[as2mo18o62] (bpy = 4,4′-bipyridine)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-12-01
description The title compound, tris(4,4′-bipyridinium) diarsenooctadecamolybdate(VI), (C10H10N2)3[As2Mo18O62], featuring protonated bipyridine molecules and a classical Dawson-type polyoxo-anion, has been synthesized under hydrothermal conditions. The polyoxoanions are linked together via the bipyridyl cations, acting as hydrogen-bond donors, generating a two-dimensional supramolecular network. The asymmetric unit contains 1.5 4,4′-bipyridinium (H2bpy) units, with an inversion centre in the central bond of the second H2bpy unit. The site symmetry of the anion is overline{1}.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809050260
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