Thiosemicarbazone Complexes of Transition Metals as Catalysts for Cross-Coupling Reactions
Catalysis of cross-coupling reactions under phosphane-free conditions represents an important ongoing challenge. Although transition metal complexes based on the thiosemicarbazone unit have been known for a very long time, their use in homogeneous catalysis has been studied only relatively recently....
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MDPI AG
2020-09-01
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| Series: | Catalysts |
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| Online Access: | https://www.mdpi.com/2073-4344/10/10/1107 |
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doaj-92588fa78ed545d195d98007f4014b072020-11-25T03:47:00ZengMDPI AGCatalysts2073-43442020-09-01101107110710.3390/catal10101107Thiosemicarbazone Complexes of Transition Metals as Catalysts for Cross-Coupling ReactionsIoannis D. Kostas0Barry R. Steele1Laboratory of Organic/Organometallic Chemistry & Catalysis, Institute of Chemical Biology, National Hellenic Research Foundation, Vas. Constantinou 48, 11635 Athens, GreeceLaboratory of Organic/Organometallic Chemistry & Catalysis, Institute of Chemical Biology, National Hellenic Research Foundation, Vas. Constantinou 48, 11635 Athens, GreeceCatalysis of cross-coupling reactions under phosphane-free conditions represents an important ongoing challenge. Although transition metal complexes based on the thiosemicarbazone unit have been known for a very long time, their use in homogeneous catalysis has been studied only relatively recently. In particular, reports of cross-coupling catalytic reactions with such complexes have appeared only in the last 15 years. This review provides a survey of the research in this area and a discussion of the prospects for future developments.https://www.mdpi.com/2073-4344/10/10/1107thiosemicarbazonemetal complextransition metal catalysiscross-coupling reactionHeck reactionSuzuki reaction |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Ioannis D. Kostas Barry R. Steele |
| spellingShingle |
Ioannis D. Kostas Barry R. Steele Thiosemicarbazone Complexes of Transition Metals as Catalysts for Cross-Coupling Reactions Catalysts thiosemicarbazone metal complex transition metal catalysis cross-coupling reaction Heck reaction Suzuki reaction |
| author_facet |
Ioannis D. Kostas Barry R. Steele |
| author_sort |
Ioannis D. Kostas |
| title |
Thiosemicarbazone Complexes of Transition Metals as Catalysts for Cross-Coupling Reactions |
| title_short |
Thiosemicarbazone Complexes of Transition Metals as Catalysts for Cross-Coupling Reactions |
| title_full |
Thiosemicarbazone Complexes of Transition Metals as Catalysts for Cross-Coupling Reactions |
| title_fullStr |
Thiosemicarbazone Complexes of Transition Metals as Catalysts for Cross-Coupling Reactions |
| title_full_unstemmed |
Thiosemicarbazone Complexes of Transition Metals as Catalysts for Cross-Coupling Reactions |
| title_sort |
thiosemicarbazone complexes of transition metals as catalysts for cross-coupling reactions |
| publisher |
MDPI AG |
| series |
Catalysts |
| issn |
2073-4344 |
| publishDate |
2020-09-01 |
| description |
Catalysis of cross-coupling reactions under phosphane-free conditions represents an important ongoing challenge. Although transition metal complexes based on the thiosemicarbazone unit have been known for a very long time, their use in homogeneous catalysis has been studied only relatively recently. In particular, reports of cross-coupling catalytic reactions with such complexes have appeared only in the last 15 years. This review provides a survey of the research in this area and a discussion of the prospects for future developments. |
| topic |
thiosemicarbazone metal complex transition metal catalysis cross-coupling reaction Heck reaction Suzuki reaction |
| url |
https://www.mdpi.com/2073-4344/10/10/1107 |
| work_keys_str_mv |
AT ioannisdkostas thiosemicarbazonecomplexesoftransitionmetalsascatalystsforcrosscouplingreactions AT barryrsteele thiosemicarbazonecomplexesoftransitionmetalsascatalystsforcrosscouplingreactions |
| _version_ |
1724503951410200576 |