Corrosion Study on Wellbore Materials for the CO<sub>2</sub> Injection Process

For reliability and safety issues of injection wells, corrosion resistance of materials used needs to be determined. Herein, representative low-cost materials, including carbon steel X70/1.8977 and low alloyed steel 1.7225, were embedded in mortar to mimic the realistic casing-mortar interface. Two...

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Bibliographic Details
Main Authors: Le Quynh Hoa, Ralph Bäßler, Dirk Bettge, Enrico Buggisch, Bernadette Nicole Schiller, Matthias Beck
Format: Article
Language:English
Published: MDPI AG 2021-01-01
Series:Processes
Subjects:
Online Access:https://www.mdpi.com/2227-9717/9/1/115
Description
Summary:For reliability and safety issues of injection wells, corrosion resistance of materials used needs to be determined. Herein, representative low-cost materials, including carbon steel X70/1.8977 and low alloyed steel 1.7225, were embedded in mortar to mimic the realistic casing-mortar interface. Two types of cement were investigated: (1) Dyckerhoff Variodur commercial Portland cement, representing a highly acidic resistant cement and (2) Wollastonite, which can react with CO<sub>2</sub> and become stable under a CO<sub>2</sub> stream due to the carbonation process. Exposure tests were performed under 10 MPa and at 333 K in artificial aquifer fluid for up to 20 weeks, revealing crevice corrosion and uniform corrosion instead of expected pitting corrosion. To clarify the role of cement, simulated pore water was made by dispersing cement powder in aquifer fluid and used as a solution to expose steels. Surface analysis, accompanied by element mapping on exposed specimens and their cross-sections, was carried out to trace the chloride intrusion and corrosion process that followed.
ISSN:2227-9717