Synthesis of triarylpyridines with sulfonate and sulfonamide moieties via a cooperative vinylogous anomeric-based oxidation

Synthesis of triarylpyridines with sulfonate and sulfonamide moieties via a cooperative vinylogous anomeric-based oxidation

Abstract Herein, novel magnetic nanoparticles with pyridinium bridges namely Fe3O4@SiO2@PCLH-TFA through a multi-step pathway were designed and synthesized. The desired catalyst and its corresponding precursors were characterized with different techniques such as Fourier transform infrared (FT-IR) s...

Full description

Bibliographic Details
Main Authors: Morteza Torabi, Mohammad Ali Zolfigol, Meysam Yarie, Behrouz Notash, Saeid Azizian, Mina Mirzaei Azandaryani
Format: Article
Language:English
Published: Nature Publishing Group 2021-08-01
Series:Scientific Reports
Online Access:https://doi.org/10.1038/s41598-021-95830-w
id doaj-922b960268614975b70f6fd9aa52641e
record_format Article
spelling doaj-922b960268614975b70f6fd9aa52641e2021-08-22T11:25:52ZengNature Publishing GroupScientific Reports2045-23222021-08-0111111910.1038/s41598-021-95830-wSynthesis of triarylpyridines with sulfonate and sulfonamide moieties via a cooperative vinylogous anomeric-based oxidationMorteza Torabi0Mohammad Ali Zolfigol1Meysam Yarie2Behrouz Notash3Saeid Azizian4Mina Mirzaei Azandaryani5Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina UniversityDepartment of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina UniversityDepartment of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina UniversityDepartment of Inorganic Chemistry and Catalysis, Shahid Beheshti UniversityDepartment of Physical Chemistry, Faculty of Chemistry, Bu-Ali Sina UniversityDepartment of Physical Chemistry, Faculty of Chemistry, Bu-Ali Sina UniversityAbstract Herein, novel magnetic nanoparticles with pyridinium bridges namely Fe3O4@SiO2@PCLH-TFA through a multi-step pathway were designed and synthesized. The desired catalyst and its corresponding precursors were characterized with different techniques such as Fourier transform infrared (FT-IR) spectroscopy, 1H NMR, 13C NMR, Mass spectroscopy, energy dispersive X-ray (EDX) analysis, thermogravimetric/derivative thermogravimetry (TG/DTG) analysis, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and vibrating sample magnetometer (VSM). In addition, the catalytic application of the prepared catalyst in the synthesis of new series of triarylpyridines bearing sulfonate and sulfonamide moieties via a cooperative vinylogous anomeric-based oxidation was highlighted. The current trend revealed that the mentioned catalyst shows high recoverability in the reported synthesis.https://doi.org/10.1038/s41598-021-95830-w
collection DOAJ
language English
format Article
sources DOAJ
author Morteza Torabi
Mohammad Ali Zolfigol
Meysam Yarie
Behrouz Notash
Saeid Azizian
Mina Mirzaei Azandaryani
spellingShingle Morteza Torabi
Mohammad Ali Zolfigol
Meysam Yarie
Behrouz Notash
Saeid Azizian
Mina Mirzaei Azandaryani
Synthesis of triarylpyridines with sulfonate and sulfonamide moieties via a cooperative vinylogous anomeric-based oxidation
Scientific Reports
author_facet Morteza Torabi
Mohammad Ali Zolfigol
Meysam Yarie
Behrouz Notash
Saeid Azizian
Mina Mirzaei Azandaryani
author_sort Morteza Torabi
title Synthesis of triarylpyridines with sulfonate and sulfonamide moieties via a cooperative vinylogous anomeric-based oxidation
title_short Synthesis of triarylpyridines with sulfonate and sulfonamide moieties via a cooperative vinylogous anomeric-based oxidation
title_full Synthesis of triarylpyridines with sulfonate and sulfonamide moieties via a cooperative vinylogous anomeric-based oxidation
title_fullStr Synthesis of triarylpyridines with sulfonate and sulfonamide moieties via a cooperative vinylogous anomeric-based oxidation
title_full_unstemmed Synthesis of triarylpyridines with sulfonate and sulfonamide moieties via a cooperative vinylogous anomeric-based oxidation
title_sort synthesis of triarylpyridines with sulfonate and sulfonamide moieties via a cooperative vinylogous anomeric-based oxidation
publisher Nature Publishing Group
series Scientific Reports
issn 2045-2322
publishDate 2021-08-01
description Abstract Herein, novel magnetic nanoparticles with pyridinium bridges namely Fe3O4@SiO2@PCLH-TFA through a multi-step pathway were designed and synthesized. The desired catalyst and its corresponding precursors were characterized with different techniques such as Fourier transform infrared (FT-IR) spectroscopy, 1H NMR, 13C NMR, Mass spectroscopy, energy dispersive X-ray (EDX) analysis, thermogravimetric/derivative thermogravimetry (TG/DTG) analysis, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and vibrating sample magnetometer (VSM). In addition, the catalytic application of the prepared catalyst in the synthesis of new series of triarylpyridines bearing sulfonate and sulfonamide moieties via a cooperative vinylogous anomeric-based oxidation was highlighted. The current trend revealed that the mentioned catalyst shows high recoverability in the reported synthesis.
url https://doi.org/10.1038/s41598-021-95830-w
work_keys_str_mv AT mortezatorabi synthesisoftriarylpyridineswithsulfonateandsulfonamidemoietiesviaacooperativevinylogousanomericbasedoxidation
AT mohammadalizolfigol synthesisoftriarylpyridineswithsulfonateandsulfonamidemoietiesviaacooperativevinylogousanomericbasedoxidation
AT meysamyarie synthesisoftriarylpyridineswithsulfonateandsulfonamidemoietiesviaacooperativevinylogousanomericbasedoxidation
AT behrouznotash synthesisoftriarylpyridineswithsulfonateandsulfonamidemoietiesviaacooperativevinylogousanomericbasedoxidation
AT saeidazizian synthesisoftriarylpyridineswithsulfonateandsulfonamidemoietiesviaacooperativevinylogousanomericbasedoxidation
AT minamirzaeiazandaryani synthesisoftriarylpyridineswithsulfonateandsulfonamidemoietiesviaacooperativevinylogousanomericbasedoxidation
_version_ 1721199772523560960

Similar Items