[N′-(5-Bromo-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ2N′,O]dimethyltin(IV)

[N′-(5-Bromo-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ2N′,O]dimethyltin(IV)

The SnIV atom in the title compound, [Sn(CH3)2(C18H11BrN2O3)], shows a distorted cis-C2NO2Sn trigonal-bipyramidal coordination geometry, with an axial O—Sn—O angle of 155.27 (9)°. The presence of an intramolecular O—H...N hydrogen...

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Main Authors: See Mun Lee, Hapipah Mohd Ali, Kong Mun Lo
Format: Article
Language:English
Published: International Union of Crystallography 2010-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810001133
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spelling doaj-9229c2d2b849419e93920c29cf6cf0462020-11-25T00:12:43ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-02-01662m161m16110.1107/S1600536810001133[N′-(5-Bromo-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ2N′,O]dimethyltin(IV)See Mun LeeHapipah Mohd AliKong Mun LoThe SnIV atom in the title compound, [Sn(CH3)2(C18H11BrN2O3)], shows a distorted cis-C2NO2Sn trigonal-bipyramidal coordination geometry, with an axial O—Sn—O angle of 155.27 (9)°. The presence of an intramolecular O—H...N hydrogen bond between the amido N atom and hydroxy H atom in the Schiff base ligand helps to stabilize the overall molecular structure. http://scripts.iucr.org/cgi-bin/paper?S1600536810001133
collection DOAJ
language English
format Article
sources DOAJ
author See Mun Lee
Hapipah Mohd Ali
Kong Mun Lo
spellingShingle See Mun Lee
Hapipah Mohd Ali
Kong Mun Lo
[N′-(5-Bromo-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ2N′,O]dimethyltin(IV)
Acta Crystallographica Section E
author_facet See Mun Lee
Hapipah Mohd Ali
Kong Mun Lo
author_sort See Mun Lee
title [N′-(5-Bromo-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ2N′,O]dimethyltin(IV)
title_short [N′-(5-Bromo-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ2N′,O]dimethyltin(IV)
title_full [N′-(5-Bromo-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ2N′,O]dimethyltin(IV)
title_fullStr [N′-(5-Bromo-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ2N′,O]dimethyltin(IV)
title_full_unstemmed [N′-(5-Bromo-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ2N′,O]dimethyltin(IV)
title_sort [n′-(5-bromo-2-oxidobenzylidene-κo)-3-hydroxy-2-naphthohydrazidato-κ2n′,o]dimethyltin(iv)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-02-01
description The SnIV atom in the title compound, [Sn(CH3)2(C18H11BrN2O3)], shows a distorted cis-C2NO2Sn trigonal-bipyramidal coordination geometry, with an axial O—Sn—O angle of 155.27 (9)°. The presence of an intramolecular O—H...N hydrogen bond between the amido N atom and hydroxy H atom in the Schiff base ligand helps to stabilize the overall molecular structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810001133
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AT hapipahmohdali namp82425bromo2oxidobenzylideneamp954o3hydroxy2naphthohydrazidatoamp9542namp8242odimethyltiniv
AT kongmunlo namp82425bromo2oxidobenzylideneamp954o3hydroxy2naphthohydrazidatoamp9542namp8242odimethyltiniv
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