Chlorido(1,2-dimethyl-1H-imidazole-κN3){2-[(diphenoxyphosphanyl)oxy]phenyl-κ2C1,P}palladium(II)

Chlorido(1,2-dimethyl-1H-imidazole-κN3){2-[(diphenoxyphosphanyl)oxy]phenyl-κ2C1,P}palladium(II)

The Pd atom in the title compound, [Pd(C18H14O3P)Cl(C5H8N2)], adopts a slightly distorted square-planar coordination geometry, with the metallated carbon positioned trans to the Cl atom. The crystal structure is stabilized by several weak C—H...O and C—H...Cl hydrogen-bon...

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Main Authors: Izabela Błaszczyk, Anna M. Trzeciak, Andrzej Gniewek
Format: Article
Language:English
Published: International Union of Crystallography 2012-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812003431
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spelling doaj-921379a220cd4ab6925836e5947bb60a2020-11-24T21:26:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-02-01682m227m22810.1107/S1600536812003431Chlorido(1,2-dimethyl-1H-imidazole-κN3){2-[(diphenoxyphosphanyl)oxy]phenyl-κ2C1,P}palladium(II)Izabela BłaszczykAnna M. TrzeciakAndrzej GniewekThe Pd atom in the title compound, [Pd(C18H14O3P)Cl(C5H8N2)], adopts a slightly distorted square-planar coordination geometry, with the metallated carbon positioned trans to the Cl atom. The crystal structure is stabilized by several weak C—H...O and C—H...Cl hydrogen-bond interactions. One of the phenyl rings is disordered over two almost equally occupied sites.http://scripts.iucr.org/cgi-bin/paper?S1600536812003431
collection DOAJ
language English
format Article
sources DOAJ
author Izabela Błaszczyk
Anna M. Trzeciak
Andrzej Gniewek
spellingShingle Izabela Błaszczyk
Anna M. Trzeciak
Andrzej Gniewek
Chlorido(1,2-dimethyl-1H-imidazole-κN3){2-[(diphenoxyphosphanyl)oxy]phenyl-κ2C1,P}palladium(II)
Acta Crystallographica Section E
author_facet Izabela Błaszczyk
Anna M. Trzeciak
Andrzej Gniewek
author_sort Izabela Błaszczyk
title Chlorido(1,2-dimethyl-1H-imidazole-κN3){2-[(diphenoxyphosphanyl)oxy]phenyl-κ2C1,P}palladium(II)
title_short Chlorido(1,2-dimethyl-1H-imidazole-κN3){2-[(diphenoxyphosphanyl)oxy]phenyl-κ2C1,P}palladium(II)
title_full Chlorido(1,2-dimethyl-1H-imidazole-κN3){2-[(diphenoxyphosphanyl)oxy]phenyl-κ2C1,P}palladium(II)
title_fullStr Chlorido(1,2-dimethyl-1H-imidazole-κN3){2-[(diphenoxyphosphanyl)oxy]phenyl-κ2C1,P}palladium(II)
title_full_unstemmed Chlorido(1,2-dimethyl-1H-imidazole-κN3){2-[(diphenoxyphosphanyl)oxy]phenyl-κ2C1,P}palladium(II)
title_sort chlorido(1,2-dimethyl-1h-imidazole-κn3){2-[(diphenoxyphosphanyl)oxy]phenyl-κ2c1,p}palladium(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-02-01
description The Pd atom in the title compound, [Pd(C18H14O3P)Cl(C5H8N2)], adopts a slightly distorted square-planar coordination geometry, with the metallated carbon positioned trans to the Cl atom. The crystal structure is stabilized by several weak C—H...O and C—H...Cl hydrogen-bond interactions. One of the phenyl rings is disordered over two almost equally occupied sites.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812003431
work_keys_str_mv AT izabelabamp322aszczyk chlorido12dimethyl1himidazoleamp954n32diphenoxyphosphanyloxyphenylamp9542c1ppalladiumii
AT annamtrzeciak chlorido12dimethyl1himidazoleamp954n32diphenoxyphosphanyloxyphenylamp9542c1ppalladiumii
AT andrzejgniewek chlorido12dimethyl1himidazoleamp954n32diphenoxyphosphanyloxyphenylamp9542c1ppalladiumii
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