Chlorido(1,2-dimethyl-1H-imidazole-κN3){2-[(diphenoxyphosphanyl)oxy]phenyl-κ2C1,P}palladium(II)

Chlorido(1,2-dimethyl-1H-imidazole-κN3){2-[(diphenoxyphosphanyl)oxy]phenyl-κ2C1,P}palladium(II)

The Pd atom in the title compound, [Pd(C18H14O3P)Cl(C5H8N2)], adopts a slightly distorted square-planar coordination geometry, with the metallated carbon positioned trans to the Cl atom. The crystal structure is stabilized by several weak C—H...O and C—H...Cl hydrogen-bon...

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Bibliographic Details
Main Authors: Izabela Błaszczyk, Anna M. Trzeciak, Andrzej Gniewek
Format: Article
Language:English
Published: International Union of Crystallography 2012-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812003431
Description
Summary:The Pd atom in the title compound, [Pd(C18H14O3P)Cl(C5H8N2)], adopts a slightly distorted square-planar coordination geometry, with the metallated carbon positioned trans to the Cl atom. The crystal structure is stabilized by several weak C—H...O and C—H...Cl hydrogen-bond interactions. One of the phenyl rings is disordered over two almost equally occupied sites.
ISSN:1600-5368

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