Dichlorido[2-(phenyliminomethyl)quinoline-N,N′]palladium(II)

In the title complex, [PdCl2(C16H12N2)], the PdII ion is coordinated by two N atoms [Pd—N 2.039 (2), 2.073 (2) Å] from a bidentate ligand and two chloride anions [Pd—Cl 2.2655 (7), 2.2991 (...

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Main Authors: William M. Motswainyana, Martin O. Onani, Abram M. Madiehe
Format: Article
Language:English
Published: International Union of Crystallography 2012-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812009130
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spelling doaj-9207298a69eb43699a4d6ccb845d3de62020-11-24T23:56:27ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-04-01684m380m38010.1107/S1600536812009130Dichlorido[2-(phenyliminomethyl)quinoline-N,N′]palladium(II)William M. MotswainyanaMartin O. OnaniAbram M. MadieheIn the title complex, [PdCl2(C16H12N2)], the PdII ion is coordinated by two N atoms [Pd—N 2.039 (2), 2.073 (2) Å] from a bidentate ligand and two chloride anions [Pd—Cl 2.2655 (7), 2.2991 (7) Å] in a distorted square-planar geometry. In the crystal, π–π interactions between the six-membered rings of the quinoline fragments [centroid–centroid distances = 3.815 (5), 3.824 (5) Å] link two molecules into centrosymmetric dimers.http://scripts.iucr.org/cgi-bin/paper?S1600536812009130
collection DOAJ
language English
format Article
sources DOAJ
author William M. Motswainyana
Martin O. Onani
Abram M. Madiehe
spellingShingle William M. Motswainyana
Martin O. Onani
Abram M. Madiehe
Dichlorido[2-(phenyliminomethyl)quinoline-N,N′]palladium(II)
Acta Crystallographica Section E
author_facet William M. Motswainyana
Martin O. Onani
Abram M. Madiehe
author_sort William M. Motswainyana
title Dichlorido[2-(phenyliminomethyl)quinoline-N,N′]palladium(II)
title_short Dichlorido[2-(phenyliminomethyl)quinoline-N,N′]palladium(II)
title_full Dichlorido[2-(phenyliminomethyl)quinoline-N,N′]palladium(II)
title_fullStr Dichlorido[2-(phenyliminomethyl)quinoline-N,N′]palladium(II)
title_full_unstemmed Dichlorido[2-(phenyliminomethyl)quinoline-N,N′]palladium(II)
title_sort dichlorido[2-(phenyliminomethyl)quinoline-n,n′]palladium(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-04-01
description In the title complex, [PdCl2(C16H12N2)], the PdII ion is coordinated by two N atoms [Pd—N 2.039 (2), 2.073 (2) Å] from a bidentate ligand and two chloride anions [Pd—Cl 2.2655 (7), 2.2991 (7) Å] in a distorted square-planar geometry. In the crystal, π–π interactions between the six-membered rings of the quinoline fragments [centroid–centroid distances = 3.815 (5), 3.824 (5) Å] link two molecules into centrosymmetric dimers.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812009130
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AT martinoonani dichlorido2phenyliminomethylquinolinennamp8242palladiumii
AT abrammmadiehe dichlorido2phenyliminomethylquinolinennamp8242palladiumii
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