Bis[2-(1H-imidazol-2-yl-κN3)-1H-imidazol-3-ium]silver(I) trinitrate

Bis[2-(1H-imidazol-2-yl-κN3)-1H-imidazol-3-ium]silver(I) trinitrate

The synthesis of the title salt, [Ag(C6H7N4)2](NO3)3, was carried out employing a 1:2 molar ratio of 2,2′-biimidazole and silver nitrate respectively. The cation has crystallographically-imposed C2 symmetry with the metal atom in an almost linear coordination environment [N&#82...

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Bibliographic Details
Main Authors: Shelonda R. Finch, Johnathan P. Harper, Amitava Choudhury, Ekkehard Sinn, Harvest L. Collier
Format: Article
Language:English
Published: International Union of Crystallography 2011-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811021799
Description
Summary:The synthesis of the title salt, [Ag(C6H7N4)2](NO3)3, was carried out employing a 1:2 molar ratio of 2,2′-biimidazole and silver nitrate respectively. The cation has crystallographically-imposed C2 symmetry with the metal atom in an almost linear coordination environment [N—Ag—N = 177.01 (17)°]. The crystal structure displays N—H...O and C—H...O hydrogen-bonding interactions.
ISSN:1600-5368

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