Crystal structure of bis[(oxalato-κ2O1,O2)(1,4,8,11-tetraazacyclotetradecane-κ4N)chromium(III)] dichromate octahydrate from synchrotron X-ray data

Crystal structure of bis[(oxalato-κ2O1,O2)(1,4,8,11-tetraazacyclotetradecane-κ4N)chromium(III)] dichromate octahydrate from synchrotron X-ray data

The asymmetric unit of the title compound, [Cr(C2O4)(C10H24N4)]2[Cr2O7]·8H2O (C10H24N4 = 1,4,8,11-tetraazacyclotetradecane, cyclam; C2O4 = oxalate, ox) contains one [Cr(ox)(cyclam)]+ cation, one half of a dichromate anion that lies about an inversion centre so that the bridging O atom is equally dis...

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Bibliographic Details
Main Authors: Dohyun Moon, Jong-Ha Choi
Format: Article
Language:English
Published: International Union of Crystallography 2017-03-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
cyclam
chromium(III) complex
bidentate oxalato ligand
cis-V conformation
dichromate anion
hydrogen bonding
synchrotron radiation
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989017002614

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http://scripts.iucr.org/cgi-bin/paper?S2056989017002614

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