Local and regional contributions to fine particulate matter in the 18 cities of Sichuan Basin, southwestern China

• Main Authors: X. Qiao, H. Guo, Y. Tang, P. Wang, W. Deng, X. Zhao, J. Hu, Q. Ying, H. Zhang
• Format: Article
• Language: English
• Published: Copernicus Publications 2019-05-01
• Series: Atmospheric Chemistry and Physics
• Online Access: https://www.atmos-chem-phys.net/19/5791/2019/acp-19-5791-2019.pdf

<p>The Sichuan Basin (SCB) is one of the regions suffering from severe air pollution in China, but fewer studies have been conducted for this region than for the more developed regions in eastern and northern China. In this study, a source-oriented version of the Community Multiscale Air Quality (CMAQ) model was used to quantify contributions from nine regions to PM<span class="inline-formula">_2.5</span> (i.e., particulate matter, PM, with an aerodynamic diameter less than 2.5&thinsp;<span class="inline-formula">µ</span>m) and its components in the 18 cities within the SCB in the winter (December  2014 to February 2015) and summer (June to August 2015). In the winter, citywide average PM<span class="inline-formula">_2.5</span> concentrations are 45–126&thinsp;<span class="inline-formula">µ</span>g&thinsp;m<span class="inline-formula">⁻³</span>, with 21&thinsp;%–51&thinsp;% and 39&thinsp;%–66&thinsp;% being due to local and nonlocal emissions, respectively. In the summer, 15&thinsp;%–45&thinsp;% and 25&thinsp;%–52&thinsp;% of citywide average PM<span class="inline-formula">_2.5</span> (14–31&thinsp;<span class="inline-formula">µ</span>g&thinsp;m<span class="inline-formula">⁻³</span>) are due to local and nonlocal emissions, respectively. Compared to primary PM (PPM), the inter-region transport of secondary inorganic aerosols (SIA), including ammonia, nitrate, and sulfate ions (<span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M9" display="inline" overflow="scroll" dspmath="mathml"><mrow class="chem"><msubsup><mi mathvariant="normal">NH</mi><mn mathvariant="normal">4</mn><mo>+</mo></msubsup></mrow></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="24pt" height="15pt" class="svg-formula" dspmath="mathimg" md5hash="9641cdd414b305565815b5b604dabf23"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="acp-19-5791-2019-ie00001.svg" width="24pt" height="15pt" src="acp-19-5791-2019-ie00001.png"/></svg:svg></span></span>, <span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M10" display="inline" overflow="scroll" dspmath="mathml"><mrow class="chem"><msubsup><mi mathvariant="normal">NO</mi><mn mathvariant="normal">3</mn><mo>-</mo></msubsup></mrow></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="25pt" height="16pt" class="svg-formula" dspmath="mathimg" md5hash="dd23f13eb24280cbe650be4567ce8571"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="acp-19-5791-2019-ie00002.svg" width="25pt" height="16pt" src="acp-19-5791-2019-ie00002.png"/></svg:svg></span></span>, and <span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M11" display="inline" overflow="scroll" dspmath="mathml"><mrow class="chem"><msubsup><mi mathvariant="normal">SO</mi><mn mathvariant="normal">4</mn><mrow><mn mathvariant="normal">2</mn><mo>-</mo></mrow></msubsup></mrow></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="29pt" height="17pt" class="svg-formula" dspmath="mathimg" md5hash="815783a157bc15e547bdd7a24388d96b"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="acp-19-5791-2019-ie00003.svg" width="29pt" height="17pt" src="acp-19-5791-2019-ie00003.png"/></svg:svg></span></span>, respectively), and their gas-phase precursors are greater. The region to the east of SCB (R7, including central and eastern China and others) is the largest contributor outside the SCB, and it can contribute approximately 80&thinsp;% of PM<span class="inline-formula">_2.5</span> in the eastern, northeastern, and southeastern rims of the SCB but only 10&thinsp;% in other SCB regions in both seasons. Under favorable transport conditions, regional transport of air pollutants from R7 could account for up to 35–100&thinsp;<span class="inline-formula">µ</span>g&thinsp;m<span class="inline-formula">⁻³</span> of PM<span class="inline-formula">_2.5</span> in each of the SCB cities in the winter. This study demonstrates that it is important to have joint emission control efforts among cities within the SCB and regions to the east in order to reduce PM<span class="inline-formula">_2.5</span> concentrations and prevent high PM<span class="inline-formula">_2.5</span> days for the entire basin.</p>