cis-Bis(2,2′-bipyridyl)dicyanatocobalt(II)

In the title complex, [Co(NCO)2(C10H8N2)2], the Co atom is coordinated by four N atoms from two 2,2′-bipyridyl ligands and two N atoms from two cyanate anions in a distorted octahedral geometry. The Co atom lies on a twofold rotation axis. The average Co—N bond length is 2.126&am...

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Bibliographic Details
Main Authors: Da-Cheng Li, Ling-Qian Kong, LI Jia
Format: Article
Language:English
Published: International Union of Crystallography 2008-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808007617
Description
Summary:In the title complex, [Co(NCO)2(C10H8N2)2], the Co atom is coordinated by four N atoms from two 2,2′-bipyridyl ligands and two N atoms from two cyanate anions in a distorted octahedral geometry. The Co atom lies on a twofold rotation axis. The average Co—N bond length is 2.126 (7) Å. Weak intermolecular C—H...O interactions lead to the formation of a three-dimensional network.
ISSN:1600-5368