[4,4′-(Ethane-1,2-diyldinitrilo)bis(pent-2-en-2-olato)]copper(II) 0.25-hydrate

[4,4′-(Ethane-1,2-diyldinitrilo)bis(pent-2-en-2-olato)]copper(II) 0.25-hydrate

In the title compound, [Cu(C12H18N2O2)]·0.25H2O, the coordination of the O,N,N′,O′-tetradentate ligand results in a cis-CuN2O2 square-planar geometry for the metal ion and the presence of two six-membered and one five-membered chelate rings. The complete comp...

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Bibliographic Details
Main Authors: Muhammad Aslam, Nighat Afza, Muhammad Nadeem Arshad, Itrat Anis, Waseem Ahmed, Ajaz Hussain
Format: Article
Language:English
Published: International Union of Crystallography 2012-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812017102
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spelling doaj-9190c1bd9a794d7789383cd6e8dc389b2020-11-24T21:28:51ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-05-01685m670m67010.1107/S1600536812017102[4,4′-(Ethane-1,2-diyldinitrilo)bis(pent-2-en-2-olato)]copper(II) 0.25-hydrateMuhammad AslamNighat AfzaMuhammad Nadeem ArshadItrat AnisWaseem AhmedAjaz HussainIn the title compound, [Cu(C12H18N2O2)]·0.25H2O, the coordination of the O,N,N′,O′-tetradentate ligand results in a cis-CuN2O2 square-planar geometry for the metal ion and the presence of two six-membered and one five-membered chelate rings. The complete complex molecule is close to planar (r.m.s. deviation = 0.047 Å). The uncoordinated water molecule (O-atom site symmetry 2) was modelled as half occupied. In the crystal, C—H...Ow and Ow—H...O (w = water) hydrogen bonds link the components into layers parallel to ab plane.http://scripts.iucr.org/cgi-bin/paper?S1600536812017102
collection DOAJ
language English
format Article
sources DOAJ
author Muhammad Aslam
Nighat Afza
Muhammad Nadeem Arshad
Itrat Anis
Waseem Ahmed
Ajaz Hussain
spellingShingle Muhammad Aslam
Nighat Afza
Muhammad Nadeem Arshad
Itrat Anis
Waseem Ahmed
Ajaz Hussain
[4,4′-(Ethane-1,2-diyldinitrilo)bis(pent-2-en-2-olato)]copper(II) 0.25-hydrate
Acta Crystallographica Section E
author_facet Muhammad Aslam
Nighat Afza
Muhammad Nadeem Arshad
Itrat Anis
Waseem Ahmed
Ajaz Hussain
author_sort Muhammad Aslam
title [4,4′-(Ethane-1,2-diyldinitrilo)bis(pent-2-en-2-olato)]copper(II) 0.25-hydrate
title_short [4,4′-(Ethane-1,2-diyldinitrilo)bis(pent-2-en-2-olato)]copper(II) 0.25-hydrate
title_full [4,4′-(Ethane-1,2-diyldinitrilo)bis(pent-2-en-2-olato)]copper(II) 0.25-hydrate
title_fullStr [4,4′-(Ethane-1,2-diyldinitrilo)bis(pent-2-en-2-olato)]copper(II) 0.25-hydrate
title_full_unstemmed [4,4′-(Ethane-1,2-diyldinitrilo)bis(pent-2-en-2-olato)]copper(II) 0.25-hydrate
title_sort [4,4′-(ethane-1,2-diyldinitrilo)bis(pent-2-en-2-olato)]copper(ii) 0.25-hydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-05-01
description In the title compound, [Cu(C12H18N2O2)]·0.25H2O, the coordination of the O,N,N′,O′-tetradentate ligand results in a cis-CuN2O2 square-planar geometry for the metal ion and the presence of two six-membered and one five-membered chelate rings. The complete complex molecule is close to planar (r.m.s. deviation = 0.047 Å). The uncoordinated water molecule (O-atom site symmetry 2) was modelled as half occupied. In the crystal, C—H...Ow and Ow—H...O (w = water) hydrogen bonds link the components into layers parallel to ab plane.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812017102
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AT nighatafza 44amp8242ethane12diyldinitrilobispent2en2olatocopperii025hydrate
AT muhammadnadeemarshad 44amp8242ethane12diyldinitrilobispent2en2olatocopperii025hydrate
AT itratanis 44amp8242ethane12diyldinitrilobispent2en2olatocopperii025hydrate
AT waseemahmed 44amp8242ethane12diyldinitrilobispent2en2olatocopperii025hydrate
AT ajazhussain 44amp8242ethane12diyldinitrilobispent2en2olatocopperii025hydrate
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