Aquabis(2-chloroacetato-κO)(1,10-phenanthroline-κ2N,N′)copper(II)

Aquabis(2-chloroacetato-κO)(1,10-phenanthroline-κ2N,N′)copper(II)

In the title complex, [Cu(C2H2ClO2)2(C12H8N2)(H2O)], the CuII ion is five-coordinated by two N atoms [Cu—N = 2.005 (2) and 2.029 (2) Å] from the 1,10-phenanthroline ligand, two O atoms [Cu—O = 1.943 (2)–1.966 (2...

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Main Authors: Changqing Chu, Jikun Li, Junshan Sun, Yanfei Li, Rongdong Yang
Format: Article
Language:English
Published: International Union of Crystallography 2008-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808000044
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spelling doaj-91770b46f56f4570b963402eaf6b44312020-11-24T21:28:58ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-02-01642m348m34810.1107/S1600536808000044Aquabis(2-chloroacetato-κO)(1,10-phenanthroline-κ2N,N′)copper(II)Changqing ChuJikun LiJunshan SunYanfei LiRongdong YangIn the title complex, [Cu(C2H2ClO2)2(C12H8N2)(H2O)], the CuII ion is five-coordinated by two N atoms [Cu—N = 2.005 (2) and 2.029 (2) Å] from the 1,10-phenanthroline ligand, two O atoms [Cu—O = 1.943 (2)–1.966 (2) Å] from two 2-chloroacetate ligands and one water molecule [Cu—O = 2.253 (2) Å] in a distorted square-pyramidal geometry. The crystal structure exhibits intermolecular O—H...O hydrogen bonds, short Cl...Cl contacts [3.334 (1) Å] and π–π interactions [centroid–centroid distance 3.621 (11) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536808000044
collection DOAJ
language English
format Article
sources DOAJ
author Changqing Chu
Jikun Li
Junshan Sun
Yanfei Li
Rongdong Yang
spellingShingle Changqing Chu
Jikun Li
Junshan Sun
Yanfei Li
Rongdong Yang
Aquabis(2-chloroacetato-κO)(1,10-phenanthroline-κ2N,N′)copper(II)
Acta Crystallographica Section E
author_facet Changqing Chu
Jikun Li
Junshan Sun
Yanfei Li
Rongdong Yang
author_sort Changqing Chu
title Aquabis(2-chloroacetato-κO)(1,10-phenanthroline-κ2N,N′)copper(II)
title_short Aquabis(2-chloroacetato-κO)(1,10-phenanthroline-κ2N,N′)copper(II)
title_full Aquabis(2-chloroacetato-κO)(1,10-phenanthroline-κ2N,N′)copper(II)
title_fullStr Aquabis(2-chloroacetato-κO)(1,10-phenanthroline-κ2N,N′)copper(II)
title_full_unstemmed Aquabis(2-chloroacetato-κO)(1,10-phenanthroline-κ2N,N′)copper(II)
title_sort aquabis(2-chloroacetato-κo)(1,10-phenanthroline-κ2n,n′)copper(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-02-01
description In the title complex, [Cu(C2H2ClO2)2(C12H8N2)(H2O)], the CuII ion is five-coordinated by two N atoms [Cu—N = 2.005 (2) and 2.029 (2) Å] from the 1,10-phenanthroline ligand, two O atoms [Cu—O = 1.943 (2)–1.966 (2) Å] from two 2-chloroacetate ligands and one water molecule [Cu—O = 2.253 (2) Å] in a distorted square-pyramidal geometry. The crystal structure exhibits intermolecular O—H...O hydrogen bonds, short Cl...Cl contacts [3.334 (1) Å] and π–π interactions [centroid–centroid distance 3.621 (11) Å].
url http://scripts.iucr.org/cgi-bin/paper?S1600536808000044
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AT junshansun aquabis2chloroacetato954o110phenanthroline9542nn8242copperii
AT yanfeili aquabis2chloroacetato954o110phenanthroline9542nn8242copperii
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