Simulations of Ion-Guiding Through Insulating Nanocapillaries of Varying Diameter: Interpretation of Experimental Results

• Main Author: Nikolaus Stolterfoht
• Format: Article
• Language: English
• Published: MDPI AG 2020-08-01
• Series: Atoms
• Subjects: nanocapillaries; PET polymer; highly charged ions; capillary guiding; time evolution
• Online Access: https://www.mdpi.com/2218-2004/8/3/48

The guiding of highly charged ions through a single nanocapillary is simulated in comparison with previous experiments performed with highly insulating polyethylene terephthalate (PET). The simulations are carried out using 3-keV Ne<inline-formula><math display="inline"><semantics><msup><mrow></mrow><mrow><mn>7</mn><mo>+</mo></mrow></msup></semantics></math></inline-formula> ions injected into capillaries with diameters ranging from 100 nm to 400 nm. In the calculations, non-linear effects are applied to model the charge transport along the capillary surface and into the bulk depleting the deposited charges from the capillary walls. In addition to the surface carrier mobility, the non-linear effects are also implemented into the bulk conductivity. A method is presented to determine the parameters of the surface charge transport and the bulk conductivity by reproducing the oscillatory structure of the mean emission angle. A common set of charge depletion rates are determined with relatively high accuracy providing confidence in the present theoretical analysis. Significant differences in the oscillatory structures, experimentally observed, are explained by the calculations. Experimental and theoretical results of the guiding power for capillaries of different diameters are compared. Finally, dynamic non-linear effects on the surface and bulk relaxation rates are determined from the simulations.