| Summary: | Abstract The interfacial instability of lithium (Li) metal is one of the critical challenges, which hinders the application of rechargeable Li metal batteries (LMBs). Designing facile and effective surface/interface is extremely important for practical LMBs manufacturing. Here, a highly stable Li anode with silver nanowires sowed in the patterned ditches via a simple calendaring process is developed. The remarkably increased electroactive surface area and the superior lithiophilic Ag seeds enable Li stripping/plating mainly inside the ditches. Benefitting from such unique structural design, the ditches‐patterned and Ag‐modified composite Li anode (D‐Ag@Li) achieves excellent cyclability under 2 mA cm−2 / 4 mAh cm−2 over 360 h cycling with low nucleation overpotential of 16 mV. Pairing with the D‐Ag@Li anode, the full cells with LiNi0.8Mn0.1Co0.1O2 and LiFePO4 (LFP) cathodes achieve long cycle life with 94.2% retention after 2000 cycles and 74.2% after 4000 cycles, respectively. Moreover, ultrasonic transmission mapping shows no gas generation for the LFP pouch full cell pouch cell based on D‐Ag@Li over prolonged cycling, demonstrating the feasibility and effectiveness of the authors' strategy for LMBs.
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