Synthesis, crystal structure and magnetism of [Cu(cyclam)Ni(NCS)4(H2O)2]n

Synthesis, crystal structure and magnetism of [Cu(cyclam)Ni(NCS)4(H2O)2]n

[Cu(cyclam)Ni(NCS)4(H2O)2]n (1) (cyclam = 1,4,8,11-tetraazacyclodecane) exhibits bent 1D crystal structure in which paramagnetic Cu(II) and Ni(II) atoms are linked by bridging μ2-NCS- ligands. The Cu(II) atom exhibit tetragonally elongated hexacoordination in the 4+2 form with one tetradentate macro...

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Bibliographic Details
Main Authors:	Kočanová Ivana, Kuchár Juraj, Orendáč Martin, Boča Roman, Černák Juraj
Format:	Article
Language:	English
Published:	Sciendo 2017-06-01
Series:	Nova Biotechnologica et Chimica
Subjects:	Copper Nickel Crystal structure Chain-like structure Magnetic properties
Online Access:	http://www.degruyter.com/view/j/nbec.2017.16.issue-1/nbec-2017-0010/nbec-2017-0010.xml?format=INT

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