[4-Carboxyimidazole-5-carboxylato(2–)-κ2N1,O5](5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) monohydrate

[4-Carboxyimidazole-5-carboxylato(2–)-κ2N1,O5](5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) monohydrate

The 4-carboxyimidazole-5-carboxylate(2−) dianion in the title compound, [Ni(C5H2N2O4)(C16H36N4)]·H2O, N,O′-chelates to the NiII atom, which shows an octahedral coordination. The macrocycle folds itself around the metal atom and binds to it through four second...

Full description

Bibliographic Details
Main Authors: Seik Weng Ng, Qiang Zhou, Guang-Chuan Ou
Format: Article
Language:English
Published: International Union of Crystallography 2009-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809046145
id doaj-8fab5bcdea064de48fd3369578f3202b
record_format Article
spelling doaj-8fab5bcdea064de48fd3369578f3202b2020-11-25T00:48:32ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-12-016512m1556m155610.1107/S1600536809046145[4-Carboxyimidazole-5-carboxylato(2–)-κ2N1,O5](5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) monohydrateSeik Weng NgQiang ZhouGuang-Chuan OuThe 4-carboxyimidazole-5-carboxylate(2−) dianion in the title compound, [Ni(C5H2N2O4)(C16H36N4)]·H2O, N,O′-chelates to the NiII atom, which shows an octahedral coordination. The macrocycle folds itself around the metal atom and binds to it through four secondary nitrogen atoms; adjacent molecules are linked by N—H...O hydrogen bonds into a linear chain. The water molecule is disordered over two positions. http://scripts.iucr.org/cgi-bin/paper?S1600536809046145
collection DOAJ
language English
format Article
sources DOAJ
author Seik Weng Ng
Qiang Zhou
Guang-Chuan Ou
spellingShingle Seik Weng Ng
Qiang Zhou
Guang-Chuan Ou
[4-Carboxyimidazole-5-carboxylato(2–)-κ2N1,O5](5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) monohydrate
Acta Crystallographica Section E
author_facet Seik Weng Ng
Qiang Zhou
Guang-Chuan Ou
author_sort Seik Weng Ng
title [4-Carboxyimidazole-5-carboxylato(2–)-κ2N1,O5](5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) monohydrate
title_short [4-Carboxyimidazole-5-carboxylato(2–)-κ2N1,O5](5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) monohydrate
title_full [4-Carboxyimidazole-5-carboxylato(2–)-κ2N1,O5](5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) monohydrate
title_fullStr [4-Carboxyimidazole-5-carboxylato(2–)-κ2N1,O5](5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) monohydrate
title_full_unstemmed [4-Carboxyimidazole-5-carboxylato(2–)-κ2N1,O5](5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N′′,N′′′)nickel(II) monohydrate
title_sort [4-carboxyimidazole-5-carboxylato(2–)-κ2n1,o5](5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4n,n′,n′′,n′′′)nickel(ii) monohydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-12-01
description The 4-carboxyimidazole-5-carboxylate(2−) dianion in the title compound, [Ni(C5H2N2O4)(C16H36N4)]·H2O, N,O′-chelates to the NiII atom, which shows an octahedral coordination. The macrocycle folds itself around the metal atom and binds to it through four secondary nitrogen atoms; adjacent molecules are linked by N—H...O hydrogen bonds into a linear chain. The water molecule is disordered over two positions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809046145
work_keys_str_mv AT seikwengng 4carboxyimidazole5carboxylato2amp8211amp9542n1o5557121214hexamethyl14811tetraazacyclotetradecaneamp9544nnamp8242namp8242amp8242namp8242amp8242amp8242nickeliimonohydrate
AT qiangzhou 4carboxyimidazole5carboxylato2amp8211amp9542n1o5557121214hexamethyl14811tetraazacyclotetradecaneamp9544nnamp8242namp8242amp8242namp8242amp8242amp8242nickeliimonohydrate
AT guangchuanou 4carboxyimidazole5carboxylato2amp8211amp9542n1o5557121214hexamethyl14811tetraazacyclotetradecaneamp9544nnamp8242namp8242amp8242namp8242amp8242amp8242nickeliimonohydrate
_version_ 1725255727050653696

Similar Items