Structural Classification of Quasi-One-Dimensional Ternary Nitrides

• Main Authors: David Andrew Headspith, Maria Grazia Francesconi
• Format: Article
• Language: English
• Published: MDPI AG 2016-11-01
• Series: Inorganics
• Subjects: nitrides; low-dimensional solids; mixed-metal compounds
• Online Access: http://www.mdpi.com/2304-6740/4/4/37

This review focuses on the crystal structural features of ternary (mixed-metal) quasi-one-dimensional nitrides i.e., nitrides containing (cation-N3−) coordination polyhedra sharing either corners, edges, or faces, arranged in linear chains, and intercalated by a counter ion. The current relevance of these nitrides, and of quasi-one-dimensional compounds in general, lies in the fact that they are closely related to the pure one-dimensional systems (i.e., nanowires), which are vastly researched for their amazing properties closely related to their low dimensionality. A number of these properties were firstly discovered in quasi-one-dimensional compounds, highlighting the importance of expanding knowledge and research in this area. Furthermore, unlike oxides, nitrides and other non-oxide compounds are less developed, hence more difficult to categorise into structural classes that can then be related to other classes of compounds, leading to a fuller picture of structure–properties relationship. Within this context, this review aims to categorise and describe a number of ternary (mixed-metal) quasi-one-dimensional nitrides according to their structural features, specifically, the polyhedra forming the one-dimensional chains.