The Effect of Dicarboxymethyl Cellulose on the Prevention of Protein Haze Formation on White Wine

• Main Authors: Diana Gago, Ricardo Chagas, Luísa M. Ferreira
• Format: Article
• Language: English
• Published: MDPI AG 2021-08-01
• Series: Beverages
• Subjects: bentonite; dicarboxymethyl cellulose; wine protein haze; cellulose derivative; sustainability
• Online Access: https://www.mdpi.com/2306-5710/7/3/57

Wine clarity is a critical aspect in the commercialization of white wines. The formation of wine haze can be attributed to the aggregation and precipitation of heat-unstable wine proteins. Bentonite fining is the commonly used method in winemaking for protein removal, but it is responsible for loss of wine volume and quality. Dicarboxymethyl cellulose (DCMC) was developed as a potential alternative to bentonite. Water-insoluble DCMC was prepared via catalyzed heterogeneous etherification using sodium chloromalonate and potassium iodide. White wine fining trials were benchmarked with different dosages of DCMC against a bentonite. A high-performance liquid chromatography method was optimized for protein quantification. The samples underwent heat stability tests to evaluate wine turbidity before and after fining. Results show that DCMC successfully reduced the wine protein content and turbidity. DCMC produced heat-stable wines with dosages higher than 0.25 g/L. The innovative application of DCMC in the wine sector shows potential due to its ability to stabilize white wines while overcoming problems associated with bentonite, such as lees production and loss of wine, contributing to a more sustainable process.