trans-(2,2′-Bipyrimidine)diiodido(isopropoxido)oxidorhenium(V)

In the title compound, [Re(C3H7O)I2O(C8H6N4)], the ReV atom adopts a distorted octahedral ReI2O2N2 geometry, with the O atoms in a trans conformation and the I atoms in a cis conformation. Two intramolecular C—H...I contacts occur. The crystal structure is stabilized by intermolecular...

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Main Author: Andrzej Kochel
Format: Article
Language:English
Published: International Union of Crystallography 2010-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809052556
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spelling doaj-8ea90d798af0403db141b69499cf34d52020-11-25T00:49:56ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-01-01661m42m4310.1107/S1600536809052556trans-(2,2′-Bipyrimidine)diiodido(isopropoxido)oxidorhenium(V)Andrzej KochelIn the title compound, [Re(C3H7O)I2O(C8H6N4)], the ReV atom adopts a distorted octahedral ReI2O2N2 geometry, with the O atoms in a trans conformation and the I atoms in a cis conformation. Two intramolecular C—H...I contacts occur. The crystal structure is stabilized by intermolecular C—H...O, C—H...N and C—H...I hydrogen bonds. http://scripts.iucr.org/cgi-bin/paper?S1600536809052556
collection DOAJ
language English
format Article
sources DOAJ
author Andrzej Kochel
spellingShingle Andrzej Kochel
trans-(2,2′-Bipyrimidine)diiodido(isopropoxido)oxidorhenium(V)
Acta Crystallographica Section E
author_facet Andrzej Kochel
author_sort Andrzej Kochel
title trans-(2,2′-Bipyrimidine)diiodido(isopropoxido)oxidorhenium(V)
title_short trans-(2,2′-Bipyrimidine)diiodido(isopropoxido)oxidorhenium(V)
title_full trans-(2,2′-Bipyrimidine)diiodido(isopropoxido)oxidorhenium(V)
title_fullStr trans-(2,2′-Bipyrimidine)diiodido(isopropoxido)oxidorhenium(V)
title_full_unstemmed trans-(2,2′-Bipyrimidine)diiodido(isopropoxido)oxidorhenium(V)
title_sort trans-(2,2′-bipyrimidine)diiodido(isopropoxido)oxidorhenium(v)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-01-01
description In the title compound, [Re(C3H7O)I2O(C8H6N4)], the ReV atom adopts a distorted octahedral ReI2O2N2 geometry, with the O atoms in a trans conformation and the I atoms in a cis conformation. Two intramolecular C—H...I contacts occur. The crystal structure is stabilized by intermolecular C—H...O, C—H...N and C—H...I hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809052556
work_keys_str_mv AT andrzejkochel trans22amp8242bipyrimidinediiodidoisopropoxidooxidorheniumv
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