trans-(2,2′-Bipyrimidine)diiodido(isopropoxido)oxidorhenium(V)

In the title compound, [Re(C3H7O)I2O(C8H6N4)], the ReV atom adopts a distorted octahedral ReI2O2N2 geometry, with the O atoms in a trans conformation and the I atoms in a cis conformation. Two intramolecular C—H...I contacts occur. The crystal structure is stabilized by intermolecular...

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Bibliographic Details
Main Author: Andrzej Kochel
Format: Article
Language:English
Published: International Union of Crystallography 2010-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809052556
Description
Summary:In the title compound, [Re(C3H7O)I2O(C8H6N4)], the ReV atom adopts a distorted octahedral ReI2O2N2 geometry, with the O atoms in a trans conformation and the I atoms in a cis conformation. Two intramolecular C—H...I contacts occur. The crystal structure is stabilized by intermolecular C—H...O, C—H...N and C—H...I hydrogen bonds.
ISSN:1600-5368